Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction

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Standard

Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction. / Andersen, Mads Peter Sulbæk; Hurley, MD; Wallington, TJ; Ball, JC; Martin, JW; Ellis, DA; Mabury, SA.

I: Chemical Physics Letters, Bind 381, Nr. 1-2, 04.11.2003, s. 14-21.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Andersen, MPS, Hurley, MD, Wallington, TJ, Ball, JC, Martin, JW, Ellis, DA & Mabury, SA 2003, 'Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction', Chemical Physics Letters, bind 381, nr. 1-2, s. 14-21. https://doi.org/10.1016/j.cplett.2003.09.085

APA

Andersen, M. P. S., Hurley, MD., Wallington, TJ., Ball, JC., Martin, JW., Ellis, DA., & Mabury, SA. (2003). Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction. Chemical Physics Letters, 381(1-2), 14-21. https://doi.org/10.1016/j.cplett.2003.09.085

Vancouver

Andersen MPS, Hurley MD, Wallington TJ, Ball JC, Martin JW, Ellis DA o.a. Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction. Chemical Physics Letters. 2003 nov. 4;381(1-2):14-21. https://doi.org/10.1016/j.cplett.2003.09.085

Author

Andersen, Mads Peter Sulbæk ; Hurley, MD ; Wallington, TJ ; Ball, JC ; Martin, JW ; Ellis, DA ; Mabury, SA. / Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction. I: Chemical Physics Letters. 2003 ; Bind 381, Nr. 1-2. s. 14-21.

Bibtex

@article{551cfa09631e443b9c1d6471bcac2c2c,
title = "Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction",
abstract = "Smog chamber/FTIR techniques were used to study the gas-phase reaction of C2F5C(O) with HO2 radicals in 100-700 Torr of air, or O-2, diluent at 296 K. The reaction proceeds by two pathways leading to formation of C2F5C(O)OH and O-3 in ayield of 24 +/- 4% and C2F5C(O)O radicals, OH radicals and O-2 in a yield of 76 +/- 4 The gas phase reaction of CnF2n+1C(O)O-2 with HO2 radicals offers a potential explanation for at least part of the observed environmental burden of fluorinated carboxylic acids, CnF2n+1C(O)OH. As part of this work an upper limit for the rate constant of reaction of Cl atorns with C2F5C(O)OH at 296 K was determined; k(Cl + C2F5C(O)OH) <1 x 10(-11) cm(3) molecule(-1) s(-1). (C) 2003 Published by Elsevier B.V.",
author = "Andersen, {Mads Peter Sulb{\ae}k} and MD Hurley and TJ Wallington and JC Ball and JW Martin and DA Ellis and SA Mabury",
year = "2003",
month = nov,
day = "4",
doi = "10.1016/j.cplett.2003.09.085",
language = "Udefineret/Ukendt",
volume = "381",
pages = "14--21",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-2",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of C2F5CHO: mechanism of the C2F5C(O)O-2+HO2 reaction

AU - Andersen, Mads Peter Sulbæk

AU - Hurley, MD

AU - Wallington, TJ

AU - Ball, JC

AU - Martin, JW

AU - Ellis, DA

AU - Mabury, SA

PY - 2003/11/4

Y1 - 2003/11/4

N2 - Smog chamber/FTIR techniques were used to study the gas-phase reaction of C2F5C(O) with HO2 radicals in 100-700 Torr of air, or O-2, diluent at 296 K. The reaction proceeds by two pathways leading to formation of C2F5C(O)OH and O-3 in ayield of 24 +/- 4% and C2F5C(O)O radicals, OH radicals and O-2 in a yield of 76 +/- 4 The gas phase reaction of CnF2n+1C(O)O-2 with HO2 radicals offers a potential explanation for at least part of the observed environmental burden of fluorinated carboxylic acids, CnF2n+1C(O)OH. As part of this work an upper limit for the rate constant of reaction of Cl atorns with C2F5C(O)OH at 296 K was determined; k(Cl + C2F5C(O)OH) <1 x 10(-11) cm(3) molecule(-1) s(-1). (C) 2003 Published by Elsevier B.V.

AB - Smog chamber/FTIR techniques were used to study the gas-phase reaction of C2F5C(O) with HO2 radicals in 100-700 Torr of air, or O-2, diluent at 296 K. The reaction proceeds by two pathways leading to formation of C2F5C(O)OH and O-3 in ayield of 24 +/- 4% and C2F5C(O)O radicals, OH radicals and O-2 in a yield of 76 +/- 4 The gas phase reaction of CnF2n+1C(O)O-2 with HO2 radicals offers a potential explanation for at least part of the observed environmental burden of fluorinated carboxylic acids, CnF2n+1C(O)OH. As part of this work an upper limit for the rate constant of reaction of Cl atorns with C2F5C(O)OH at 296 K was determined; k(Cl + C2F5C(O)OH) <1 x 10(-11) cm(3) molecule(-1) s(-1). (C) 2003 Published by Elsevier B.V.

U2 - 10.1016/j.cplett.2003.09.085

DO - 10.1016/j.cplett.2003.09.085

M3 - Tidsskriftartikel

VL - 381

SP - 14

EP - 21

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-2

ER -

ID: 44568546