Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2

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Standard

Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2. / Wallington, Timothy J.; Sehested, Jens; Nielsen, Ole J.

I: Chemical Physics Letters, Bind 226, Nr. 5-6, 26.08.1994, s. 563-569.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Wallington, TJ, Sehested, J & Nielsen, OJ 1994, 'Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2', Chemical Physics Letters, bind 226, nr. 5-6, s. 563-569. https://doi.org/10.1016/0009-2614(94)00751-9

APA

Wallington, T. J., Sehested, J., & Nielsen, O. J. (1994). Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2. Chemical Physics Letters, 226(5-6), 563-569. https://doi.org/10.1016/0009-2614(94)00751-9

Vancouver

Wallington TJ, Sehested J, Nielsen OJ. Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2. Chemical Physics Letters. 1994 aug. 26;226(5-6):563-569. https://doi.org/10.1016/0009-2614(94)00751-9

Author

Wallington, Timothy J. ; Sehested, Jens ; Nielsen, Ole J. / Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2. I: Chemical Physics Letters. 1994 ; Bind 226, Nr. 5-6. s. 563-569.

Bibtex

@article{f7a3c77cd1004dbca191aaaaceb35718,
title = "Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2",
abstract = "A pulse radiolysis technique has been used to measure a rate constant of (6.6±1.3) x 10-12 cm3 molecule-1 s-1 for the association reaction between CF3C(O)O2 radicals and NO2 at 295 K and one atmosphere total pressure of SF6 diluent. A FTIR/smog chamber system was used to study the thermal decomposition CF3C(O)O2NO2. The rate of decomposition of CF3C(O)O2NO2 was independent of the total pressure of N2 diluent over the range 100-700 Torr and was fit by the expression k-1=(1.9-1.5 +7.6)x1016 exp[(-14000±480)/T] s-1. Implications for the atmospheric chemistry of CFC replacements are discussed.",
author = "Wallington, {Timothy J.} and Jens Sehested and Nielsen, {Ole J.}",
year = "1994",
month = aug,
day = "26",
doi = "10.1016/0009-2614(94)00751-9",
language = "English",
volume = "226",
pages = "563--569",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "5-6",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of CF3C(O)O2 radicals. Kinetics of their reaction with NO2 and kinetics of the thermal decomposition of the product CF3C(O)O2NO2

AU - Wallington, Timothy J.

AU - Sehested, Jens

AU - Nielsen, Ole J.

PY - 1994/8/26

Y1 - 1994/8/26

N2 - A pulse radiolysis technique has been used to measure a rate constant of (6.6±1.3) x 10-12 cm3 molecule-1 s-1 for the association reaction between CF3C(O)O2 radicals and NO2 at 295 K and one atmosphere total pressure of SF6 diluent. A FTIR/smog chamber system was used to study the thermal decomposition CF3C(O)O2NO2. The rate of decomposition of CF3C(O)O2NO2 was independent of the total pressure of N2 diluent over the range 100-700 Torr and was fit by the expression k-1=(1.9-1.5 +7.6)x1016 exp[(-14000±480)/T] s-1. Implications for the atmospheric chemistry of CFC replacements are discussed.

AB - A pulse radiolysis technique has been used to measure a rate constant of (6.6±1.3) x 10-12 cm3 molecule-1 s-1 for the association reaction between CF3C(O)O2 radicals and NO2 at 295 K and one atmosphere total pressure of SF6 diluent. A FTIR/smog chamber system was used to study the thermal decomposition CF3C(O)O2NO2. The rate of decomposition of CF3C(O)O2NO2 was independent of the total pressure of N2 diluent over the range 100-700 Torr and was fit by the expression k-1=(1.9-1.5 +7.6)x1016 exp[(-14000±480)/T] s-1. Implications for the atmospheric chemistry of CFC replacements are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0001579645&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(94)00751-9

DO - 10.1016/0009-2614(94)00751-9

M3 - Journal article

AN - SCOPUS:0001579645

VL - 226

SP - 563

EP - 569

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 5-6

ER -

ID: 228194427