Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene. / Andersen, Mads Peter Sulbæk; Ponomarev, DA; Nielsen, OJ; Hurley, MD; Wallington, TJ.
I: Chemical Physics Letters, Bind 350, Nr. 5-6, 28.12.2001, s. 423-426.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Kinetics and mechanism of the gas phase reaction of Cl atoms with iodobenzene
AU - Andersen, Mads Peter Sulbæk
AU - Ponomarev, DA
AU - Nielsen, OJ
AU - Hurley, MD
AU - Wallington, TJ
PY - 2001/12/28
Y1 - 2001/12/28
N2 - Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20-700 Torr of N-2, air, or O-2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl + QH(5)I) = (3.3 +/- 0.7) x 10(-11) cm(3) molecule(-1) s(-1) to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100 The title reaction proceeds via a displacement mechanism (probably addition followed by elimination). (C) 2001 Elsevier Science B.V. All rights reserved.
AB - Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with iodobenzene (C6H5I) in 20-700 Torr of N-2, air, or O-2 diluent at 296 K. The reaction proceeds with a rate constant k(Cl + QH(5)I) = (3.3 +/- 0.7) x 10(-11) cm(3) molecule(-1) s(-1) to give chlorobenzene (C6H5Cl) in a yield which is indistinguishable from 100 The title reaction proceeds via a displacement mechanism (probably addition followed by elimination). (C) 2001 Elsevier Science B.V. All rights reserved.
M3 - Tidsskriftartikel
VL - 350
SP - 423
EP - 426
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 5-6
ER -
ID: 44568381