Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2

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Standard

Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2. / Anastasi, Christopher; Broomfield, Mark; Nielsen, Ole John; Pagsberg, Palle.

I: The Journal of Physical Chemistry, Bind 96, Nr. 2, 01.12.1992, s. 696-701.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Anastasi, C, Broomfield, M, Nielsen, OJ & Pagsberg, P 1992, 'Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2', The Journal of Physical Chemistry, bind 96, nr. 2, s. 696-701.

APA

Anastasi, C., Broomfield, M., Nielsen, O. J., & Pagsberg, P. (1992). Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2. The Journal of Physical Chemistry, 96(2), 696-701.

Vancouver

Anastasi C, Broomfield M, Nielsen OJ, Pagsberg P. Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2. The Journal of Physical Chemistry. 1992 dec. 1;96(2):696-701.

Author

Anastasi, Christopher ; Broomfield, Mark ; Nielsen, Ole John ; Pagsberg, Palle. / Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2. I: The Journal of Physical Chemistry. 1992 ; Bind 96, Nr. 2. s. 696-701.

Bibtex

@article{34842b92963c4b48808bf97fa022f836,
title = "Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2",
abstract = "The pulse radiolysis/kinetic absorption technique has been used to study the reactions of CH2SH with O2, NO, and NO2. Rate constants of 8.5 × 10-12, 1.9 × 10-11, and 3.5 × 10-11 cm3 molecule-1 s-1, respectively, were obtained at 1 atm and 298 K. Absorption spectra due to product species indicated that the reaction with O2 proceeds via addition. There is evidence to suggest that addition is also the pathway for the NO and NO2 reactions.",
author = "Christopher Anastasi and Mark Broomfield and Nielsen, {Ole John} and Palle Pagsberg",
year = "1992",
month = dec,
day = "1",
language = "English",
volume = "96",
pages = "696--701",
journal = "Journal of Physical Chemistry",
issn = "0022-3654",
publisher = "American Chemical Society",
number = "2",

}

RIS

TY - JOUR

T1 - Kinetics and mechanisms of the reactions of CH2SH radicals with O2, NO, and NO2

AU - Anastasi, Christopher

AU - Broomfield, Mark

AU - Nielsen, Ole John

AU - Pagsberg, Palle

PY - 1992/12/1

Y1 - 1992/12/1

N2 - The pulse radiolysis/kinetic absorption technique has been used to study the reactions of CH2SH with O2, NO, and NO2. Rate constants of 8.5 × 10-12, 1.9 × 10-11, and 3.5 × 10-11 cm3 molecule-1 s-1, respectively, were obtained at 1 atm and 298 K. Absorption spectra due to product species indicated that the reaction with O2 proceeds via addition. There is evidence to suggest that addition is also the pathway for the NO and NO2 reactions.

AB - The pulse radiolysis/kinetic absorption technique has been used to study the reactions of CH2SH with O2, NO, and NO2. Rate constants of 8.5 × 10-12, 1.9 × 10-11, and 3.5 × 10-11 cm3 molecule-1 s-1, respectively, were obtained at 1 atm and 298 K. Absorption spectra due to product species indicated that the reaction with O2 proceeds via addition. There is evidence to suggest that addition is also the pathway for the NO and NO2 reactions.

UR - http://www.scopus.com/inward/record.url?scp=0011083748&partnerID=8YFLogxK

M3 - Journal article

AN - SCOPUS:0011083748

VL - 96

SP - 696

EP - 701

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

SN - 0022-3654

IS - 2

ER -

ID: 228196504