Cyclodextrin Aldehydes are Oxidase Mimics

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Cyclodextrin Aldehydes are Oxidase Mimics. / Fenger, Thomas Hauch; Bjerre, Jeannette; Bols, Mikael.

I: ChemBioChem, Bind 10, Nr. 15, 2009, s. 2494.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Harvard

Fenger, TH, Bjerre, J & Bols, M 2009, 'Cyclodextrin Aldehydes are Oxidase Mimics', ChemBioChem, bind 10, nr. 15, s. 2494. https://doi.org/10.1002/cbic.200900448

APA

Fenger, T. H., Bjerre, J., & Bols, M. (2009). Cyclodextrin Aldehydes are Oxidase Mimics. ChemBioChem, 10(15), 2494. https://doi.org/10.1002/cbic.200900448

Vancouver

Fenger TH, Bjerre J, Bols M. Cyclodextrin Aldehydes are Oxidase Mimics. ChemBioChem. 2009;10(15):2494. https://doi.org/10.1002/cbic.200900448

Author

Fenger, Thomas Hauch ; Bjerre, Jeannette ; Bols, Mikael. / Cyclodextrin Aldehydes are Oxidase Mimics. I: ChemBioChem. 2009 ; Bind 10, Nr. 15. s. 2494.

Bibtex

@article{252d5d20b4af11debc73000ea68e967b,
title = "Cyclodextrin Aldehydes are Oxidase Mimics",
abstract = "Cyclodextrins containing 6-aldehyde groups were found to catalyse oxidation of aminophenols in the presence of hydrogen peroxide. The catalysis followed Michaelis-Menten kinetics and is related to the catalysis previously observed with cyclodextrin ketones. A range of different cyclodextrin aldehydes were prepared containing one, two or more aldehydes at the primary rim (6-positions) or a ethoxy-2-al or propoxy-3-al at the secondary rim. 2-O-ethoxy-2-al--cyclodextrin was found to be the best catalyst. The aldehydes are in many cases better catalysts than the ketones, because of their powerful covalent binding of hydrogen peroxide.",
author = "Fenger, {Thomas Hauch} and Jeannette Bjerre and Mikael Bols",
note = "Paper id:: http://dx.doi.org/10.1002/cbic.200900448",
year = "2009",
doi = "http://dx.doi.org/10.1002/cbic.200900448",
language = "English",
volume = "10",
pages = "2494",
journal = "ChemBioChem",
issn = "1439-4227",
publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",
number = "15",

}

RIS

TY - JOUR

T1 - Cyclodextrin Aldehydes are Oxidase Mimics

AU - Fenger, Thomas Hauch

AU - Bjerre, Jeannette

AU - Bols, Mikael

N1 - Paper id:: http://dx.doi.org/10.1002/cbic.200900448

PY - 2009

Y1 - 2009

N2 - Cyclodextrins containing 6-aldehyde groups were found to catalyse oxidation of aminophenols in the presence of hydrogen peroxide. The catalysis followed Michaelis-Menten kinetics and is related to the catalysis previously observed with cyclodextrin ketones. A range of different cyclodextrin aldehydes were prepared containing one, two or more aldehydes at the primary rim (6-positions) or a ethoxy-2-al or propoxy-3-al at the secondary rim. 2-O-ethoxy-2-al--cyclodextrin was found to be the best catalyst. The aldehydes are in many cases better catalysts than the ketones, because of their powerful covalent binding of hydrogen peroxide.

AB - Cyclodextrins containing 6-aldehyde groups were found to catalyse oxidation of aminophenols in the presence of hydrogen peroxide. The catalysis followed Michaelis-Menten kinetics and is related to the catalysis previously observed with cyclodextrin ketones. A range of different cyclodextrin aldehydes were prepared containing one, two or more aldehydes at the primary rim (6-positions) or a ethoxy-2-al or propoxy-3-al at the secondary rim. 2-O-ethoxy-2-al--cyclodextrin was found to be the best catalyst. The aldehydes are in many cases better catalysts than the ketones, because of their powerful covalent binding of hydrogen peroxide.

U2 - http://dx.doi.org/10.1002/cbic.200900448

DO - http://dx.doi.org/10.1002/cbic.200900448

M3 - Journal article

VL - 10

SP - 2494

JO - ChemBioChem

JF - ChemBioChem

SN - 1439-4227

IS - 15

ER -

ID: 14996969