Accurate Calculations of OH-Stretching Intensities with a Reduced-Dimensional Local Mode Model Including Eckart Axis Embedding

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Absolute OH- and OD-stretching transition intensities have been calculated for a series of alcohols (methanol, ethanol, 2-propanol, 1-propanol, and tert-butanol) with one-dimensional (1D) and three-dimensional (3D) local mode models. We compare the calculated intensities for the ΔvOH = 1-5 and ΔvOD = 1-3 transitions with experimental values. Potential energy and dipole moment surfaces are calculated at the CCSD(T)-F12a/VDZ-F12 level of theory. The 1D local mode model includes only the OH(D)-stretching mode, whereas the 3D local mode model also includes the CO-stretching and COH(D)-bending modes. We analyze the effect on vibrational intensities of using either a molecule-fixed Eckart frame or a space-fixed Cartesian frame. We find that both Eckart embedding and inclusion of the CO-stretching and COH(D)-bending modes in the local mode model are important for the OH/OD-stretching fundamental transition intensities, but have a minor effect on overtone intensities. The 3D reduced-dimensional local model, when combined with coupled cluster surfaces, accurately predicts OH/OD-stretching transition intensities and wavenumbers, for all alcohols included in this work.

OriginalsprogEngelsk
TidsskriftJournal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory
Vol/bind124
Udgave nummer5
Sider (fra-til)932-942
Antal sider11
ISSN1089-5639
DOI
StatusUdgivet - 6 feb. 2020

ID: 243195462