Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy
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- Direct observation of Mg2+ complexes in ionic liquid solutions by 31Mg β-NMR spectroscopy
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NMR spectra of Mg2+ ions in ionic liquids were recorded using a highly sensitive variant of NMR spectroscopy known as β-NMR. The β-NMR spectra of MgCl2 in EMIM-Ac and EMIM-DCA compare favourably with conventional NMR, and exhibit linewidths of ∼3 ppm, allowing for discrimination of species with oxygen and nitrogen coordination.
Originalsprog | Engelsk |
---|---|
Tidsskrift | Dalton Transactions |
Vol/bind | 47 |
Udgave nummer | 41 |
Sider (fra-til) | 14431-14435 |
Antal sider | 5 |
ISSN | 1477-9226 |
DOI | |
Status | Udgivet - 2018 |
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ID: 204351880