Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf)

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Standard

Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf). / Thomsen, Ditte Linde; Andersen, Vibeke Friis; Nielsen, Ole John; Wallington, Timothy.

I: {PHYSICAL CHEMISTRY CHEMICAL PHYSICS}, Bind 13, Nr. 7, 2011, s. 2758-2764.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Thomsen, DL, Andersen, VF, Nielsen, OJ & Wallington, T 2011, 'Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf)', {PHYSICAL CHEMISTRY CHEMICAL PHYSICS}, bind 13, nr. 7, s. 2758-2764. https://doi.org/10.1039/c0cp01609h

APA

Thomsen, D. L., Andersen, V. F., Nielsen, O. J., & Wallington, T. (2011). Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf). {PHYSICAL CHEMISTRY CHEMICAL PHYSICS}, 13(7), 2758-2764. https://doi.org/10.1039/c0cp01609h

Vancouver

Thomsen DL, Andersen VF, Nielsen OJ, Wallington T. Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf). {PHYSICAL CHEMISTRY CHEMICAL PHYSICS}. 2011;13(7):2758-2764. https://doi.org/10.1039/c0cp01609h

Author

Thomsen, Ditte Linde ; Andersen, Vibeke Friis ; Nielsen, Ole John ; Wallington, Timothy. / Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf). I: {PHYSICAL CHEMISTRY CHEMICAL PHYSICS}. 2011 ; Bind 13, Nr. 7. s. 2758-2764.

Bibtex

@article{fe7e6dce140c4b55a632bdb05484813f,
title = "Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf)",
abstract = "FTIR smog chamber techniques were used to measure k(Cl + C2F5CH2OCH3) = (2.52 ± 0.37) × 10−11 and k(OH + C2F5CH2OCH3) = (5.78 ± 1.02) × 10−13 cm3 molecule−1 s−1 in 700 Torr of air diluent at 296 ± 1 K. The atmospheric lifetime of C2F5CH2OCH3 is estimated to be 20 days. Reaction of chlorine atoms with C2F5CH2OCH3 proceeds 18 ± 2% at the –CH2– group and 82 ± 2% at the –CH3 group. Reaction of OH radicals with C2F5CH2OCH3 proceeds 44 ± 5% at the –CH2– group and 56 ± 5% at the –CH3 group. The atmospheric fate of C2F5CH2OCH2O radicals is reaction with O2 to give C2F5CH2OCHO. The atmospheric fate of C2F5CH(O)OCH3 radicals is C–C bond-cleavage to give C2F5 radicals and CH3OCHO (methyl formate). The infrared spectrum was recorded and used to estimate a global warming potential of 6 (100 year time horizon) for C2F5CH2OCH3.",
author = "Thomsen, {Ditte Linde} and Andersen, {Vibeke Friis} and Nielsen, {Ole John} and Timothy Wallington",
year = "2011",
doi = "10.1039/c0cp01609h",
language = "English",
volume = "13",
pages = "2758--2764",
journal = "Physical Chemistry Chemical Physics",
issn = "1463-9076",
publisher = "Royal Society of Chemistry",
number = "7",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of C2F5CH2OCH3 (HFE-365mcf)

AU - Thomsen, Ditte Linde

AU - Andersen, Vibeke Friis

AU - Nielsen, Ole John

AU - Wallington, Timothy

PY - 2011

Y1 - 2011

N2 - FTIR smog chamber techniques were used to measure k(Cl + C2F5CH2OCH3) = (2.52 ± 0.37) × 10−11 and k(OH + C2F5CH2OCH3) = (5.78 ± 1.02) × 10−13 cm3 molecule−1 s−1 in 700 Torr of air diluent at 296 ± 1 K. The atmospheric lifetime of C2F5CH2OCH3 is estimated to be 20 days. Reaction of chlorine atoms with C2F5CH2OCH3 proceeds 18 ± 2% at the –CH2– group and 82 ± 2% at the –CH3 group. Reaction of OH radicals with C2F5CH2OCH3 proceeds 44 ± 5% at the –CH2– group and 56 ± 5% at the –CH3 group. The atmospheric fate of C2F5CH2OCH2O radicals is reaction with O2 to give C2F5CH2OCHO. The atmospheric fate of C2F5CH(O)OCH3 radicals is C–C bond-cleavage to give C2F5 radicals and CH3OCHO (methyl formate). The infrared spectrum was recorded and used to estimate a global warming potential of 6 (100 year time horizon) for C2F5CH2OCH3.

AB - FTIR smog chamber techniques were used to measure k(Cl + C2F5CH2OCH3) = (2.52 ± 0.37) × 10−11 and k(OH + C2F5CH2OCH3) = (5.78 ± 1.02) × 10−13 cm3 molecule−1 s−1 in 700 Torr of air diluent at 296 ± 1 K. The atmospheric lifetime of C2F5CH2OCH3 is estimated to be 20 days. Reaction of chlorine atoms with C2F5CH2OCH3 proceeds 18 ± 2% at the –CH2– group and 82 ± 2% at the –CH3 group. Reaction of OH radicals with C2F5CH2OCH3 proceeds 44 ± 5% at the –CH2– group and 56 ± 5% at the –CH3 group. The atmospheric fate of C2F5CH2OCH2O radicals is reaction with O2 to give C2F5CH2OCHO. The atmospheric fate of C2F5CH(O)OCH3 radicals is C–C bond-cleavage to give C2F5 radicals and CH3OCHO (methyl formate). The infrared spectrum was recorded and used to estimate a global warming potential of 6 (100 year time horizon) for C2F5CH2OCH3.

U2 - 10.1039/c0cp01609h

DO - 10.1039/c0cp01609h

M3 - Journal article

VL - 13

SP - 2758

EP - 2764

JO - Physical Chemistry Chemical Physics

JF - Physical Chemistry Chemical Physics

SN - 1463-9076

IS - 7

ER -

ID: 37856936