Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact

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Standard

Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2 : lifetimes, degradation products, and enviromental impact. / Toft, A. M.; Hurley, M. D.; Wallington, T. J.; Andersen, Mads Peter Sulbæk; Nielsen, Ole John.

I: Chemical Physics Letters, Bind 427, Nr. 1-3, 2006, s. 41-46.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Toft, AM, Hurley, MD, Wallington, TJ, Andersen, MPS & Nielsen, OJ 2006, 'Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact', Chemical Physics Letters, bind 427, nr. 1-3, s. 41-46. https://doi.org/10.1016/j.cplett.2006.06.047

APA

Toft, A. M., Hurley, M. D., Wallington, T. J., Andersen, M. P. S., & Nielsen, O. J. (2006). Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact. Chemical Physics Letters, 427(1-3), 41-46. https://doi.org/10.1016/j.cplett.2006.06.047

Vancouver

Toft AM, Hurley MD, Wallington TJ, Andersen MPS, Nielsen OJ. Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact. Chemical Physics Letters. 2006;427(1-3):41-46. https://doi.org/10.1016/j.cplett.2006.06.047

Author

Toft, A. M. ; Hurley, M. D. ; Wallington, T. J. ; Andersen, Mads Peter Sulbæk ; Nielsen, Ole John. / Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2 : lifetimes, degradation products, and enviromental impact. I: Chemical Physics Letters. 2006 ; Bind 427, Nr. 1-3. s. 41-46.

Bibtex

@article{612e0a6fd4fa40b6b35038928b8eb42b,
title = "Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2: lifetimes, degradation products, and enviromental impact",
abstract = "FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.",
author = "Toft, {A. M.} and Hurley, {M. D.} and Wallington, {T. J.} and Andersen, {Mads Peter Sulb{\ae}k} and Nielsen, {Ole John}",
year = "2006",
doi = "10.1016/j.cplett.2006.06.047",
language = "English",
volume = "427",
pages = "41--46",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "1-3",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of C4F9O(CH2)3OC4F9 and CF3CFHCF2O (CH2)3OCF3CFHCF2

T2 - lifetimes, degradation products, and enviromental impact

AU - Toft, A. M.

AU - Hurley, M. D.

AU - Wallington, T. J.

AU - Andersen, Mads Peter Sulbæk

AU - Nielsen, Ole John

PY - 2006

Y1 - 2006

N2 - FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.

AB - FTIR smog chamber techniques were used to measure k(Cl + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.97 +/- 0.17) x 10(-12) k(OH + CF3CFHCF2O(CH2)(3)OCF2CFHCF3) = (2.45 +/- 0.14) x 10(-13), k(Cl + C4F9O(CH2)(3)OC4F9) = (1.45 +/- 0.16) x 10(-12), and k(OH + C4F9O(CH2)(3)OC4F9) = (1.44 +/- 0.10) x 10(-13) cm(3) molecule(-1) s(-1) in 700 Torr of air at 296 K. The atmospheric lifetimes of CF3CFHCF2O(CH2)(3)OCF(2)ZCFHCF(3) and C4F9O(CH2)(3)OC4F9 with respect to reaction with OH radicals are estimated to be 46 and 83 days, respectively. In 700 Torr of N2/02 diluent at 296 K, decomposition via C-C bond scission and reaction with O-2 are competing loss mechanisms for the alkoxy radicals ROCH(O-.)CH2CH2OR and ROCH2CH(O-.)CH2OR (R = C4F9, CF3CFHCF2). (c) 2006 Elsevier B.V. All rights reserved.

U2 - 10.1016/j.cplett.2006.06.047

DO - 10.1016/j.cplett.2006.06.047

M3 - Journal article

VL - 427

SP - 41

EP - 46

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 1-3

ER -

ID: 44568172