Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction

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Standard

Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction. / Møgelberg, Trine E.; Nielsen, Ole J.; Sehested, Jens; Wallington, Timothy J.; Hurley, Michael D.; Schneider, William F.

I: Chemical Physics Letters, Bind 225, Nr. 4-6, 05.08.1994, s. 375-380.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Møgelberg, TE, Nielsen, OJ, Sehested, J, Wallington, TJ, Hurley, MD & Schneider, WF 1994, 'Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction', Chemical Physics Letters, bind 225, nr. 4-6, s. 375-380. https://doi.org/10.1016/0009-2614(94)87097-7

APA

Møgelberg, T. E., Nielsen, O. J., Sehested, J., Wallington, T. J., Hurley, M. D., & Schneider, W. F. (1994). Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction. Chemical Physics Letters, 225(4-6), 375-380. https://doi.org/10.1016/0009-2614(94)87097-7

Vancouver

Møgelberg TE, Nielsen OJ, Sehested J, Wallington TJ, Hurley MD, Schneider WF. Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction. Chemical Physics Letters. 1994 aug. 5;225(4-6):375-380. https://doi.org/10.1016/0009-2614(94)87097-7

Author

Møgelberg, Trine E. ; Nielsen, Ole J. ; Sehested, Jens ; Wallington, Timothy J. ; Hurley, Michael D. ; Schneider, William F. / Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction. I: Chemical Physics Letters. 1994 ; Bind 225, Nr. 4-6. s. 375-380.

Bibtex

@article{13189a96482542f0b6282a43ce5dc23a,
title = "Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction",
abstract = "A pulse radiolysis system was used to study the kinetics of the reaction of CF3CFHO2 with NO2. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be k=(5.0±0.5)×10-12 cm3 molecule-1 s-1. A long path length Fourier-transform infrared technique was used to investigate the thermal decomposition of the product CF3CFHO2NO2. At 296 K in the presence of 700 Torr of air, decomposition of CF3CFHO2NO2 was rapid (greater than 90% decomposition within 3 min). The results are discussed in the context of atmospheric chemistry of CF3CFH2 (HFC-134a).",
author = "M{\o}gelberg, {Trine E.} and Nielsen, {Ole J.} and Jens Sehested and Wallington, {Timothy J.} and Hurley, {Michael D.} and Schneider, {William F.}",
year = "1994",
month = aug,
day = "5",
doi = "10.1016/0009-2614(94)87097-7",
language = "English",
volume = "225",
pages = "375--380",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "4-6",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of HFC-134a. Kinetic and mechanistic study of the CF3CFHO2+NO2 reaction

AU - Møgelberg, Trine E.

AU - Nielsen, Ole J.

AU - Sehested, Jens

AU - Wallington, Timothy J.

AU - Hurley, Michael D.

AU - Schneider, William F.

PY - 1994/8/5

Y1 - 1994/8/5

N2 - A pulse radiolysis system was used to study the kinetics of the reaction of CF3CFHO2 with NO2. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be k=(5.0±0.5)×10-12 cm3 molecule-1 s-1. A long path length Fourier-transform infrared technique was used to investigate the thermal decomposition of the product CF3CFHO2NO2. At 296 K in the presence of 700 Torr of air, decomposition of CF3CFHO2NO2 was rapid (greater than 90% decomposition within 3 min). The results are discussed in the context of atmospheric chemistry of CF3CFH2 (HFC-134a).

AB - A pulse radiolysis system was used to study the kinetics of the reaction of CF3CFHO2 with NO2. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be k=(5.0±0.5)×10-12 cm3 molecule-1 s-1. A long path length Fourier-transform infrared technique was used to investigate the thermal decomposition of the product CF3CFHO2NO2. At 296 K in the presence of 700 Torr of air, decomposition of CF3CFHO2NO2 was rapid (greater than 90% decomposition within 3 min). The results are discussed in the context of atmospheric chemistry of CF3CFH2 (HFC-134a).

UR - http://www.scopus.com/inward/record.url?scp=0038127677&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(94)87097-7

DO - 10.1016/0009-2614(94)87097-7

M3 - Journal article

AN - SCOPUS:0038127677

VL - 225

SP - 375

EP - 380

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -

ID: 228193251