Kinetics and mechanism of the reaction of CF3 radicals with NO2

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Standard

Kinetics and mechanism of the reaction of CF3 radicals with NO2. / Sehested, Jens; Nielsen, Ole John; Rinaldi, Carlos A.; Lane, Silvia I.; Ferrero, Juan Carlos.

I: International Journal of Chemical Kinetics, Bind 28, Nr. 8, 01.01.1996, s. 579-588.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Sehested, J, Nielsen, OJ, Rinaldi, CA, Lane, SI & Ferrero, JC 1996, 'Kinetics and mechanism of the reaction of CF3 radicals with NO2', International Journal of Chemical Kinetics, bind 28, nr. 8, s. 579-588. https://doi.org/10.1002/(SICI)1097-4601(1996)28:8<579::AID-KIN3>3.0.CO;2-S

APA

Sehested, J., Nielsen, O. J., Rinaldi, C. A., Lane, S. I., & Ferrero, J. C. (1996). Kinetics and mechanism of the reaction of CF3 radicals with NO2. International Journal of Chemical Kinetics, 28(8), 579-588. https://doi.org/10.1002/(SICI)1097-4601(1996)28:8<579::AID-KIN3>3.0.CO;2-S

Vancouver

Sehested J, Nielsen OJ, Rinaldi CA, Lane SI, Ferrero JC. Kinetics and mechanism of the reaction of CF3 radicals with NO2. International Journal of Chemical Kinetics. 1996 jan. 1;28(8):579-588. https://doi.org/10.1002/(SICI)1097-4601(1996)28:8<579::AID-KIN3>3.0.CO;2-S

Author

Sehested, Jens ; Nielsen, Ole John ; Rinaldi, Carlos A. ; Lane, Silvia I. ; Ferrero, Juan Carlos. / Kinetics and mechanism of the reaction of CF3 radicals with NO2. I: International Journal of Chemical Kinetics. 1996 ; Bind 28, Nr. 8. s. 579-588.

Bibtex

@article{e1e4412ab3bb4d01bb446aace2d4d09f,
title = "Kinetics and mechanism of the reaction of CF3 radicals with NO2",
abstract = "The reaction of CF3 with NO2 was studied at 296 ± 2K using two different absolute techniques. Absolute rate constants of (1.6 ± 0.3) × 10-11 and (2.1-0.3+0.7) × 10-11 cm3 molecule-1 s-1 were derived by IR fluorescence and UV absorption spectroscopy, respectively. The reaction proceeds via two reaction channels: CF3 + NO2 → CF2O + FNO, (70 ± 12)% and CF3 + NO2 → CF3O + NO, (30 ± 12)%. An upper limit of 11% for formation of other reaction products was determined. The overall rate constant was within the uncertainty independent of total pressure between 0.4 to 760 torr.",
author = "Jens Sehested and Nielsen, {Ole John} and Rinaldi, {Carlos A.} and Lane, {Silvia I.} and Ferrero, {Juan Carlos}",
year = "1996",
month = jan,
day = "1",
doi = "10.1002/(SICI)1097-4601(1996)28:8<579::AID-KIN3>3.0.CO;2-S",
language = "English",
volume = "28",
pages = "579--588",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "JohnWiley & Sons, Inc.",
number = "8",

}

RIS

TY - JOUR

T1 - Kinetics and mechanism of the reaction of CF3 radicals with NO2

AU - Sehested, Jens

AU - Nielsen, Ole John

AU - Rinaldi, Carlos A.

AU - Lane, Silvia I.

AU - Ferrero, Juan Carlos

PY - 1996/1/1

Y1 - 1996/1/1

N2 - The reaction of CF3 with NO2 was studied at 296 ± 2K using two different absolute techniques. Absolute rate constants of (1.6 ± 0.3) × 10-11 and (2.1-0.3+0.7) × 10-11 cm3 molecule-1 s-1 were derived by IR fluorescence and UV absorption spectroscopy, respectively. The reaction proceeds via two reaction channels: CF3 + NO2 → CF2O + FNO, (70 ± 12)% and CF3 + NO2 → CF3O + NO, (30 ± 12)%. An upper limit of 11% for formation of other reaction products was determined. The overall rate constant was within the uncertainty independent of total pressure between 0.4 to 760 torr.

AB - The reaction of CF3 with NO2 was studied at 296 ± 2K using two different absolute techniques. Absolute rate constants of (1.6 ± 0.3) × 10-11 and (2.1-0.3+0.7) × 10-11 cm3 molecule-1 s-1 were derived by IR fluorescence and UV absorption spectroscopy, respectively. The reaction proceeds via two reaction channels: CF3 + NO2 → CF2O + FNO, (70 ± 12)% and CF3 + NO2 → CF3O + NO, (30 ± 12)%. An upper limit of 11% for formation of other reaction products was determined. The overall rate constant was within the uncertainty independent of total pressure between 0.4 to 760 torr.

UR - http://www.scopus.com/inward/record.url?scp=0030212448&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1097-4601(1996)28:8<579::AID-KIN3>3.0.CO;2-S

DO - 10.1002/(SICI)1097-4601(1996)28:8<579::AID-KIN3>3.0.CO;2-S

M3 - Journal article

AN - SCOPUS:0030212448

VL - 28

SP - 579

EP - 588

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 8

ER -

ID: 223681501