Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K

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Standard

Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K. / Ellermann, Thomas; Sehested, Jens; Nielsen, Ole John; Pagsberg, Palle; Wallington, Timothy J.

I: Chemical Physics Letters, Bind 218, Nr. 4, 18.02.1994, s. 287-294.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Ellermann, T, Sehested, J, Nielsen, OJ, Pagsberg, P & Wallington, TJ 1994, 'Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K', Chemical Physics Letters, bind 218, nr. 4, s. 287-294. https://doi.org/10.1016/0009-2614(94)00006-9

APA

Ellermann, T., Sehested, J., Nielsen, O. J., Pagsberg, P., & Wallington, T. J. (1994). Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K. Chemical Physics Letters, 218(4), 287-294. https://doi.org/10.1016/0009-2614(94)00006-9

Vancouver

Ellermann T, Sehested J, Nielsen OJ, Pagsberg P, Wallington TJ. Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K. Chemical Physics Letters. 1994 feb. 18;218(4):287-294. https://doi.org/10.1016/0009-2614(94)00006-9

Author

Ellermann, Thomas ; Sehested, Jens ; Nielsen, Ole John ; Pagsberg, Palle ; Wallington, Timothy J. / Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K. I: Chemical Physics Letters. 1994 ; Bind 218, Nr. 4. s. 287-294.

Bibtex

@article{3f50dd565fc54074936464fc7f14ed14,
title = "Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K",
abstract = "The ultraviolet absorption spectrum of FO2 radicals and the kinetics of the reaction of F atoms with O2 have been studied in the gas phase at 295 K using pulse radiolysis combined with kinetic UV spectroscopy. At 230 nm, σFO2 =(5.08±0.70)×10-18 cm2 molecule-1. The kinetics of the reaction F+O2+M→FO2+M (1), were investigated over the pressure range 200-1000 mbar of SF6 diluent. At 1 atm total pressure the pseudo-second-order rate constant for reaction (1) was determined to be (1.9±0.3)×10-13 cm3 molecule-1 s-1.",
author = "Thomas Ellermann and Jens Sehested and Nielsen, {Ole John} and Palle Pagsberg and Wallington, {Timothy J.}",
year = "1994",
month = feb,
day = "18",
doi = "10.1016/0009-2614(94)00006-9",
language = "English",
volume = "218",
pages = "287--294",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "4",

}

RIS

TY - JOUR

T1 - Kinetics of the reaction of F atoms with O2 and UV spectrum of FO2 radicals in the gas phase at 295 K

AU - Ellermann, Thomas

AU - Sehested, Jens

AU - Nielsen, Ole John

AU - Pagsberg, Palle

AU - Wallington, Timothy J.

PY - 1994/2/18

Y1 - 1994/2/18

N2 - The ultraviolet absorption spectrum of FO2 radicals and the kinetics of the reaction of F atoms with O2 have been studied in the gas phase at 295 K using pulse radiolysis combined with kinetic UV spectroscopy. At 230 nm, σFO2 =(5.08±0.70)×10-18 cm2 molecule-1. The kinetics of the reaction F+O2+M→FO2+M (1), were investigated over the pressure range 200-1000 mbar of SF6 diluent. At 1 atm total pressure the pseudo-second-order rate constant for reaction (1) was determined to be (1.9±0.3)×10-13 cm3 molecule-1 s-1.

AB - The ultraviolet absorption spectrum of FO2 radicals and the kinetics of the reaction of F atoms with O2 have been studied in the gas phase at 295 K using pulse radiolysis combined with kinetic UV spectroscopy. At 230 nm, σFO2 =(5.08±0.70)×10-18 cm2 molecule-1. The kinetics of the reaction F+O2+M→FO2+M (1), were investigated over the pressure range 200-1000 mbar of SF6 diluent. At 1 atm total pressure the pseudo-second-order rate constant for reaction (1) was determined to be (1.9±0.3)×10-13 cm3 molecule-1 s-1.

UR - http://www.scopus.com/inward/record.url?scp=0001499977&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(94)00006-9

DO - 10.1016/0009-2614(94)00006-9

M3 - Journal article

AN - SCOPUS:0001499977

VL - 218

SP - 287

EP - 294

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4

ER -

ID: 228194609