Magnetic Archimedean Tessellations in Metal–Organic Frameworks
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Magnetic Archimedean Tessellations in Metal–Organic Frameworks. / Chen, Hua; Voigt, Laura; Kubus, Mariusz; Mihrin, Dmytro; Mossin, Susanne; Larsen, René W.; Kegnæs, Søren; Piligkos, Stergios; Pedersen, Kasper S.
I: Journal of the American Chemical Society, Bind 143, Nr. 35, 08.09.2021, s. 14041-14045.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Magnetic Archimedean Tessellations in Metal–Organic Frameworks
AU - Chen, Hua
AU - Voigt, Laura
AU - Kubus, Mariusz
AU - Mihrin, Dmytro
AU - Mossin, Susanne
AU - Larsen, René W.
AU - Kegnæs, Søren
AU - Piligkos, Stergios
AU - Pedersen, Kasper S.
PY - 2021/9/8
Y1 - 2021/9/8
N2 - he self-assembly of lanthanide ions with ditopic organic spacers results in the formation of complex tiling patterns that mimic the structural motifs of quasi-periodic 2D materials. The linking of trans-{LnI2}+ nodes (Ln = Gd, Dy) by both closed-shell and anion radicals of 4,4′-bipyridine affords rare examples of Archimedean tessellations in a metal–organic framework. We furthermore demonstrate the occurrence of sizable magnetic exchange interactions and slow relaxation of magnetization behavior in a complex tessellation pattern. The implementation of Archimedean tessellations in lanthanide(III) coordination solids couriers a strategy to design elusive quasi-periodic metal–organic frameworks with inimitable magnetic properties.
AB - he self-assembly of lanthanide ions with ditopic organic spacers results in the formation of complex tiling patterns that mimic the structural motifs of quasi-periodic 2D materials. The linking of trans-{LnI2}+ nodes (Ln = Gd, Dy) by both closed-shell and anion radicals of 4,4′-bipyridine affords rare examples of Archimedean tessellations in a metal–organic framework. We furthermore demonstrate the occurrence of sizable magnetic exchange interactions and slow relaxation of magnetization behavior in a complex tessellation pattern. The implementation of Archimedean tessellations in lanthanide(III) coordination solids couriers a strategy to design elusive quasi-periodic metal–organic frameworks with inimitable magnetic properties.
U2 - 10.1021/jacs.1c05057
DO - 10.1021/jacs.1c05057
M3 - Journal article
C2 - 34374526
VL - 143
SP - 14041
EP - 14045
JO - Journal of the American Chemical Society
JF - Journal of the American Chemical Society
SN - 0002-7863
IS - 35
ER -
ID: 280232062