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Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects. / Angelis, Yiannis S.; Hatzakis, Nikos S.; Smonou, Ioulia; Orfanopoulos, Michael.
I:
Tetrahedron Letters, Bind 42, Nr. 22, 2001, s. 3753-3756.
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
Angelis, YS
, Hatzakis, NS, Smonou, I & Orfanopoulos, M 2001, '
Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects',
Tetrahedron Letters, bind 42, nr. 22, s. 3753-3756.
https://doi.org/10.1016/S0040-4039(01)00539-1APA
Angelis, Y. S.
, Hatzakis, N. S., Smonou, I., & Orfanopoulos, M. (2001).
Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects.
Tetrahedron Letters,
42(22), 3753-3756.
https://doi.org/10.1016/S0040-4039(01)00539-1Vancouver
Angelis YS
, Hatzakis NS, Smonou I, Orfanopoulos M.
Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects.
Tetrahedron Letters. 2001;42(22):3753-3756.
https://doi.org/10.1016/S0040-4039(01)00539-1Author
Angelis, Yiannis S. ; Hatzakis, Nikos S. ; Smonou, Ioulia ; Orfanopoulos, Michael. / Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects. I: Tetrahedron Letters. 2001 ; Bind 42, Nr. 22. s. 3753-3756.
Bibtex
@article{75796ebf67a34f1dad552708585a9a03,
title = "Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects",
abstract = "The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.",
keywords = "Dioxiranes, Isotope effects, Mechanisms",
author = "Angelis, {Yiannis S.} and Hatzakis, {Nikos S.} and Ioulia Smonou and Michael Orfanopoulos",
note = "Funding Information: We thank the Greek Secretariat of Research and Technology (ΠENEΔ 1999 to I.S. and ΠENEΔ 1999 to M.O.) for financial support and for a research fellowship to Y.S.A. and N.S.H. Professor W. Adam is also acknowledged for valuable comments.",
year = "2001",
doi = "10.1016/S0040-4039(01)00539-1",
language = "English",
volume = "42",
pages = "3753--3756",
journal = "Tetrahedron Letters",
issn = "0040-4039",
publisher = "Pergamon Press",
number = "22",
}
RIS
TY - JOUR
T1 - Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects
AU - Angelis, Yiannis S.
AU - Hatzakis, Nikos S.
AU - Smonou, Ioulia
AU - Orfanopoulos, Michael
N1 - Funding Information:
We thank the Greek Secretariat of Research and Technology (ΠENEΔ 1999 to I.S. and ΠENEΔ 1999 to M.O.) for financial support and for a research fellowship to Y.S.A. and N.S.H. Professor W. Adam is also acknowledged for valuable comments.
PY - 2001
Y1 - 2001
N2 - The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.
AB - The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.
KW - Dioxiranes
KW - Isotope effects
KW - Mechanisms
U2 - 10.1016/S0040-4039(01)00539-1
DO - 10.1016/S0040-4039(01)00539-1
M3 - Journal article
AN - SCOPUS:0035962969
VL - 42
SP - 3753
EP - 3756
JO - Tetrahedron Letters
JF - Tetrahedron Letters
SN - 0040-4039
IS - 22
ER -
