Oxidation of benzyl alcohols by dimethyldioxirane. The question of concerted versus stepwise mechanisms probed by kinetic isotope effects
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
The primary and β-secondary kinetic isotope effects in the oxidation of secondary alcohols with dimethyl dioxirane were measured. The substantial primary and the absence of a β-secondary kinetic isotope effect support a concerted mechanism for the title reaction.
| Originalsprog | Engelsk |
|---|---|
| Tidsskrift | Tetrahedron Letters |
| Vol/bind | 42 |
| Udgave nummer | 22 |
| Sider (fra-til) | 3753-3756 |
| Antal sider | 4 |
| ISSN | 0040-4039 |
| DOI | |
| Status | Udgivet - 2001 |
| Eksternt udgivet | Ja |
ID: 286412620