Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K

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Standard

Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K. / Kelly, Christina; Treacy, Jack; Sidebottom, Howard W.; Nielsen, Ole John.

I: Chemical Physics Letters, Bind 207, Nr. 4-6, 28.05.1993, s. 498-503.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Kelly, C, Treacy, J, Sidebottom, HW & Nielsen, OJ 1993, 'Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K', Chemical Physics Letters, bind 207, nr. 4-6, s. 498-503. https://doi.org/10.1016/0009-2614(93)89036-H

APA

Kelly, C., Treacy, J., Sidebottom, H. W., & Nielsen, O. J. (1993). Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K. Chemical Physics Letters, 207(4-6), 498-503. https://doi.org/10.1016/0009-2614(93)89036-H

Vancouver

Kelly C, Treacy J, Sidebottom HW, Nielsen OJ. Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K. Chemical Physics Letters. 1993 maj 28;207(4-6):498-503. https://doi.org/10.1016/0009-2614(93)89036-H

Author

Kelly, Christina ; Treacy, Jack ; Sidebottom, Howard W. ; Nielsen, Ole John. / Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K. I: Chemical Physics Letters. 1993 ; Bind 207, Nr. 4-6. s. 498-503.

Bibtex

@article{a2c457af77854c7bb37cd14276032c05,
title = "Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K",
abstract = "Rate constant ratios of the reactions of CF3O radicals with a number of hydrocarbons have been determined at 298 ± 2 K and atmospheric pressure using a relative rate method. Using a previously determined value k(CF3O+C2H6) = 1.2×10-12 cm3 molecule-1 s-1 these rate constant ratios provide estimates of the rate constants: k(CF3O+CH4) = (1.2±0.1)×10-14, k(CF3O+c-C3H6) = (3.6±0.2)×10-13, k(CF3O+C3H8) = (4.7±0.7)×10-12, k(CF3O+(CH3)3CH) = (7.2±0.5)×10-12, k(CF3O+C2H4) = (3.0±0.1)×10-11 and k(CF3O+C6H6) = (3.6±0.1)×10-11 cm3 molecule-1 s-1. The importance of the reactions of CF3O radicals with hydrocarbons under atmospheric conditions is discussed.",
author = "Christina Kelly and Jack Treacy and Sidebottom, {Howard W.} and Nielsen, {Ole John}",
year = "1993",
month = may,
day = "28",
doi = "10.1016/0009-2614(93)89036-H",
language = "English",
volume = "207",
pages = "498--503",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "4-6",

}

RIS

TY - JOUR

T1 - Rate constants for the reaction of CF3O radicals with hydrocarbons at 298 K

AU - Kelly, Christina

AU - Treacy, Jack

AU - Sidebottom, Howard W.

AU - Nielsen, Ole John

PY - 1993/5/28

Y1 - 1993/5/28

N2 - Rate constant ratios of the reactions of CF3O radicals with a number of hydrocarbons have been determined at 298 ± 2 K and atmospheric pressure using a relative rate method. Using a previously determined value k(CF3O+C2H6) = 1.2×10-12 cm3 molecule-1 s-1 these rate constant ratios provide estimates of the rate constants: k(CF3O+CH4) = (1.2±0.1)×10-14, k(CF3O+c-C3H6) = (3.6±0.2)×10-13, k(CF3O+C3H8) = (4.7±0.7)×10-12, k(CF3O+(CH3)3CH) = (7.2±0.5)×10-12, k(CF3O+C2H4) = (3.0±0.1)×10-11 and k(CF3O+C6H6) = (3.6±0.1)×10-11 cm3 molecule-1 s-1. The importance of the reactions of CF3O radicals with hydrocarbons under atmospheric conditions is discussed.

AB - Rate constant ratios of the reactions of CF3O radicals with a number of hydrocarbons have been determined at 298 ± 2 K and atmospheric pressure using a relative rate method. Using a previously determined value k(CF3O+C2H6) = 1.2×10-12 cm3 molecule-1 s-1 these rate constant ratios provide estimates of the rate constants: k(CF3O+CH4) = (1.2±0.1)×10-14, k(CF3O+c-C3H6) = (3.6±0.2)×10-13, k(CF3O+C3H8) = (4.7±0.7)×10-12, k(CF3O+(CH3)3CH) = (7.2±0.5)×10-12, k(CF3O+C2H4) = (3.0±0.1)×10-11 and k(CF3O+C6H6) = (3.6±0.1)×10-11 cm3 molecule-1 s-1. The importance of the reactions of CF3O radicals with hydrocarbons under atmospheric conditions is discussed.

UR - http://www.scopus.com/inward/record.url?scp=24844469029&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(93)89036-H

DO - 10.1016/0009-2614(93)89036-H

M3 - Journal article

AN - SCOPUS:24844469029

VL - 207

SP - 498

EP - 503

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 4-6

ER -

ID: 228195214