Sn(IV)-corroles reversibly bind carboxylates in the axial position
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Sn(IV)-corroles reversibly bind carboxylates in the axial position. / Bak, Helle; Cavigli, Paolo; Bond, Andrew; Brock-Nannestad, Theis; Pittelkow, Michael; Iengo, Elisabetta.
I: Journal of Porphyrins and Phthalocyanines, Bind 27, Nr. 07n10, 2023.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Sn(IV)-corroles reversibly bind carboxylates in the axial position
AU - Bak, Helle
AU - Cavigli, Paolo
AU - Bond, Andrew
AU - Brock-Nannestad, Theis
AU - Pittelkow, Michael
AU - Iengo, Elisabetta
N1 - Publisher Copyright: © 2023 World Scientific Publishing Company.
PY - 2023
Y1 - 2023
N2 - We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using 1H NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.
AB - We present the synthesis of Sn(IV)-corrole complexes that bind to carboxylate moieties reversibly, via axial ligation. The systems have been predominantly characterized using 1H NMR spectroscopy, X-ray crystallography, and MALDI mass spectrometry. The dynamic nature of the Sn(IV)-O2CR bond has been studied in solution using 2D-NMR spectroscopy.
KW - carboxylate
KW - corrole
KW - exchange
KW - NMR
KW - Sn
KW - supramolecular
KW - x-ray
U2 - 10.1142/S1088424623501080
DO - 10.1142/S1088424623501080
M3 - Journal article
AN - SCOPUS:85165896670
VL - 27
JO - Journal of Porphyrins and Phthalocyanines
JF - Journal of Porphyrins and Phthalocyanines
SN - 1088-4246
IS - 07n10
ER -
ID: 361690146