Silylated Sugars – Synthesis and Properties
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Silylated Sugars – Synthesis and Properties. / Bols, Mikael; Frihed, Tobias Gylling; Pedersen, Martin Jæger; Pedersen, Christian Marcus.
I: Synlett, Bind 33, Nr. 5, 2022, s. 415-428.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Silylated Sugars – Synthesis and Properties
AU - Bols, Mikael
AU - Frihed, Tobias Gylling
AU - Pedersen, Martin Jæger
AU - Pedersen, Christian Marcus
PY - 2022
Y1 - 2022
N2 - Silicon has been used in carbohydrate chemistry for half a century, but mostly as a protective group for sugar alcohols. Recently, the use of silicon has expanded to functionalization via C–H activation, conformational arming of glycosyl donors, and conformational alteration of carbohydrates. Silicon has proven useful as more than a protective group and during the last one and a half decades we have demonstrated how it influences both the reactivity of glycosyl donors and stereochemical outcome of glycosylations. Silicon can also be attached directly to the sugar C-backbone, which has even more pronounced effects on the chemistry and properties of the molecules. In this Account, we will give a tour through our work involving silicon and carbohydrates.
AB - Silicon has been used in carbohydrate chemistry for half a century, but mostly as a protective group for sugar alcohols. Recently, the use of silicon has expanded to functionalization via C–H activation, conformational arming of glycosyl donors, and conformational alteration of carbohydrates. Silicon has proven useful as more than a protective group and during the last one and a half decades we have demonstrated how it influences both the reactivity of glycosyl donors and stereochemical outcome of glycosylations. Silicon can also be attached directly to the sugar C-backbone, which has even more pronounced effects on the chemistry and properties of the molecules. In this Account, we will give a tour through our work involving silicon and carbohydrates.
U2 - 10.1055/s-0040-1719854
DO - 10.1055/s-0040-1719854
M3 - Journal article
VL - 33
SP - 415
EP - 428
JO - SYNLETT: Accounts and Rapid Communications in Chemical Synthesis
JF - SYNLETT: Accounts and Rapid Communications in Chemical Synthesis
SN - 0936-5214
IS - 5
ER -
ID: 285452857