Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts

Publikation: Bidrag til tidsskrift › Letter › Forskning › fagfællebedømt

Standard

Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts. / Cepitis, Ritums; Ivaništšev, Vladislav; Rossmeisl, Jan; Kongi, Nadezda.

I: Catalysis Science and Technology, Bind 14, Nr. 8, 2024, s. 2105–2113.

Publikation: Bidrag til tidsskrift › Letter › Forskning › fagfællebedømt

Harvard

Cepitis, R, Ivaništšev, V, Rossmeisl, J & Kongi, N 2024, 'Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts', Catalysis Science and Technology, bind 14, nr. 8, s. 2105–2113. https://doi.org/10.1039/d4cy00036f

APA

Cepitis, R., Ivaništšev, V., Rossmeisl, J., & Kongi, N. (2024). Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts. Catalysis Science and Technology, 14(8), 2105–2113. https://doi.org/10.1039/d4cy00036f

Vancouver

Cepitis R, Ivaništšev V, Rossmeisl J, Kongi N. Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts. Catalysis Science and Technology. 2024;14(8):2105–2113. https://doi.org/10.1039/d4cy00036f

Author

Cepitis, Ritums ; Ivaništšev, Vladislav ; Rossmeisl, Jan ; Kongi, Nadezda. / Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts. I: Catalysis Science and Technology. 2024 ; Bind 14, Nr. 8. s. 2105–2113.

Bibtex

@article{407ac1d2159b40de9223a499c95fc0df,

title = "Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts",

abstract = "This communication introduces the concept of geometry-adaptive electrocatalysis, where a catalyst adjusts its geometry during the reaction. A model system of metal-nitrogen-carbon (M-N-C) catalysts - the dual-atom site 2Co-N4 of variable curvature - proves the concept from the first principles. Density functional theory calculations show how cycling the curvature effect with a geometry adaptation bypasses the scaling relations. Thus, in theory, geometry-adaptive electrocatalysis offers a promising direction to address the current stagnation in the experimentally measured overpotential for oxygen evolution and reduction reactions. It also indicates the possibility of discovering the ideal oxygen electrocatalyst.",

author = "Ritums Cepitis and Vladislav Ivani{\v s}t{\v s}ev and Jan Rossmeisl and Nadezda Kongi",

note = "Publisher Copyright: {\textcopyright} 2024 The Royal Society of Chemistry",

year = "2024",

doi = "10.1039/d4cy00036f",

language = "English",

volume = "14",

pages = "2105–2113",

journal = "Catalysis Science and Technology",

issn = "2044-4753",

publisher = "Royal Society of Chemistry",

number = "8",

}

RIS

TY - JOUR

T1 - Bypassing the scaling relations in oxygen electrocatalysis with geometry-adaptive catalysts

AU - Cepitis, Ritums

AU - Ivaništšev, Vladislav

AU - Rossmeisl, Jan

AU - Kongi, Nadezda

PY - 2024

Y1 - 2024

N2 - This communication introduces the concept of geometry-adaptive electrocatalysis, where a catalyst adjusts its geometry during the reaction. A model system of metal-nitrogen-carbon (M-N-C) catalysts - the dual-atom site 2Co-N4 of variable curvature - proves the concept from the first principles. Density functional theory calculations show how cycling the curvature effect with a geometry adaptation bypasses the scaling relations. Thus, in theory, geometry-adaptive electrocatalysis offers a promising direction to address the current stagnation in the experimentally measured overpotential for oxygen evolution and reduction reactions. It also indicates the possibility of discovering the ideal oxygen electrocatalyst.

AB - This communication introduces the concept of geometry-adaptive electrocatalysis, where a catalyst adjusts its geometry during the reaction. A model system of metal-nitrogen-carbon (M-N-C) catalysts - the dual-atom site 2Co-N4 of variable curvature - proves the concept from the first principles. Density functional theory calculations show how cycling the curvature effect with a geometry adaptation bypasses the scaling relations. Thus, in theory, geometry-adaptive electrocatalysis offers a promising direction to address the current stagnation in the experimentally measured overpotential for oxygen evolution and reduction reactions. It also indicates the possibility of discovering the ideal oxygen electrocatalyst.

U2 - 10.1039/d4cy00036f

DO - 10.1039/d4cy00036f

M3 - Letter

AN - SCOPUS:85188017227

VL - 14

SP - 2105

EP - 2113

JO - Catalysis Science and Technology

JF - Catalysis Science and Technology

SN - 2044-4753

IS - 8

ER -

ID: 389362215

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