Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries

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Standard

Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries. / Martins, Milena; Haering, Dominik; Connell, Justin G.; Wan, Hao; Svane, Katrine L.; Genorio, Bostjan; Farinazzo Bergamo Dias Martins, Pedro; Lopes, Pietro P.; Gould, Brian; Maglia, Filippo; Jung, Roland; Stamenkovic, Vojislav; Castelli, Ivano E.; Markovic, Nenad M.; Rossmeisl, Jan; Strmcnik, Dusan.

I: ACS Catalysis, Bind 13, Nr. 13, 2023, s. 9289-9301.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Martins, M, Haering, D, Connell, JG, Wan, H, Svane, KL, Genorio, B, Farinazzo Bergamo Dias Martins, P, Lopes, PP, Gould, B, Maglia, F, Jung, R, Stamenkovic, V, Castelli, IE, Markovic, NM, Rossmeisl, J & Strmcnik, D 2023, 'Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries', ACS Catalysis, bind 13, nr. 13, s. 9289-9301. https://doi.org/10.1021/acscatal.3c01531

APA

Martins, M., Haering, D., Connell, J. G., Wan, H., Svane, K. L., Genorio, B., Farinazzo Bergamo Dias Martins, P., Lopes, P. P., Gould, B., Maglia, F., Jung, R., Stamenkovic, V., Castelli, I. E., Markovic, N. M., Rossmeisl, J., & Strmcnik, D. (2023). Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries. ACS Catalysis, 13(13), 9289-9301. https://doi.org/10.1021/acscatal.3c01531

Vancouver

Martins M, Haering D, Connell JG, Wan H, Svane KL, Genorio B o.a. Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries. ACS Catalysis. 2023;13(13):9289-9301. https://doi.org/10.1021/acscatal.3c01531

Author

Martins, Milena ; Haering, Dominik ; Connell, Justin G. ; Wan, Hao ; Svane, Katrine L. ; Genorio, Bostjan ; Farinazzo Bergamo Dias Martins, Pedro ; Lopes, Pietro P. ; Gould, Brian ; Maglia, Filippo ; Jung, Roland ; Stamenkovic, Vojislav ; Castelli, Ivano E. ; Markovic, Nenad M. ; Rossmeisl, Jan ; Strmcnik, Dusan. / Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries. I: ACS Catalysis. 2023 ; Bind 13, Nr. 13. s. 9289-9301.

Bibtex

@article{efe4790127b24211af095bcfe2a407b3,
title = "Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries",
abstract = "Compared to aqueous electrolytes, fundamental understanding of the chemical and electrochemical processes occurring in non-aqueous electrolytes is far less developed. This is no different for Li-ion battery (LiB) electrolytes, where many questions regarding the solid-electrolyte interphase (SEI) on the anode side remain unanswered, including its chemical composition, the mechanism of formation, and its impact on LiB performance. Here, we present a detailed experimental and theoretical study of the electrochemistry of ethylene carbonate (EC) and its chemical relationship with trace amounts of water and HF across a vast range of electrode materials, from well-ordered single crystals to realistic graphite electrodes. We reveal the electrocatalytic nature of EC, HF, and water electroreductions at all interfaces, and unveil the catalytic role of water in EC electroreduction. Moreover, we show that these reactions are connected in a closed cycle by chemical reactions that take place either at the electrode/electrolyte interface or in the bulk of the electrolyte and demonstrate that the composition of the SEI depends predominantly on the balance between the (electro)chemistry of EC, water, and HF.",
author = "Milena Martins and Dominik Haering and Connell, {Justin G.} and Hao Wan and Svane, {Katrine L.} and Bostjan Genorio and {Farinazzo Bergamo Dias Martins}, Pedro and Lopes, {Pietro P.} and Brian Gould and Filippo Maglia and Roland Jung and Vojislav Stamenkovic and Castelli, {Ivano E.} and Markovic, {Nenad M.} and Jan Rossmeisl and Dusan Strmcnik",
year = "2023",
doi = "10.1021/acscatal.3c01531",
language = "English",
volume = "13",
pages = "9289--9301",
journal = "ACS Catalysis",
issn = "2155-5435",
publisher = "American Chemical Society",
number = "13",

}

RIS

TY - JOUR

T1 - Role of Catalytic Conversions of Ethylene Carbonate, Water, and HF in Forming the Solid-Electrolyte Interphase of Li-Ion Batteries

AU - Martins, Milena

AU - Haering, Dominik

AU - Connell, Justin G.

AU - Wan, Hao

AU - Svane, Katrine L.

AU - Genorio, Bostjan

AU - Farinazzo Bergamo Dias Martins, Pedro

AU - Lopes, Pietro P.

AU - Gould, Brian

AU - Maglia, Filippo

AU - Jung, Roland

AU - Stamenkovic, Vojislav

AU - Castelli, Ivano E.

AU - Markovic, Nenad M.

AU - Rossmeisl, Jan

AU - Strmcnik, Dusan

PY - 2023

Y1 - 2023

N2 - Compared to aqueous electrolytes, fundamental understanding of the chemical and electrochemical processes occurring in non-aqueous electrolytes is far less developed. This is no different for Li-ion battery (LiB) electrolytes, where many questions regarding the solid-electrolyte interphase (SEI) on the anode side remain unanswered, including its chemical composition, the mechanism of formation, and its impact on LiB performance. Here, we present a detailed experimental and theoretical study of the electrochemistry of ethylene carbonate (EC) and its chemical relationship with trace amounts of water and HF across a vast range of electrode materials, from well-ordered single crystals to realistic graphite electrodes. We reveal the electrocatalytic nature of EC, HF, and water electroreductions at all interfaces, and unveil the catalytic role of water in EC electroreduction. Moreover, we show that these reactions are connected in a closed cycle by chemical reactions that take place either at the electrode/electrolyte interface or in the bulk of the electrolyte and demonstrate that the composition of the SEI depends predominantly on the balance between the (electro)chemistry of EC, water, and HF.

AB - Compared to aqueous electrolytes, fundamental understanding of the chemical and electrochemical processes occurring in non-aqueous electrolytes is far less developed. This is no different for Li-ion battery (LiB) electrolytes, where many questions regarding the solid-electrolyte interphase (SEI) on the anode side remain unanswered, including its chemical composition, the mechanism of formation, and its impact on LiB performance. Here, we present a detailed experimental and theoretical study of the electrochemistry of ethylene carbonate (EC) and its chemical relationship with trace amounts of water and HF across a vast range of electrode materials, from well-ordered single crystals to realistic graphite electrodes. We reveal the electrocatalytic nature of EC, HF, and water electroreductions at all interfaces, and unveil the catalytic role of water in EC electroreduction. Moreover, we show that these reactions are connected in a closed cycle by chemical reactions that take place either at the electrode/electrolyte interface or in the bulk of the electrolyte and demonstrate that the composition of the SEI depends predominantly on the balance between the (electro)chemistry of EC, water, and HF.

U2 - 10.1021/acscatal.3c01531

DO - 10.1021/acscatal.3c01531

M3 - Journal article

VL - 13

SP - 9289

EP - 9301

JO - ACS Catalysis

JF - ACS Catalysis

SN - 2155-5435

IS - 13

ER -

ID: 359082960