Absolute rate constants for the gas-phase reaction of OH radicals with cyclohexane and ethane at 295 K
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Absolute rate constants for the gas-phase reaction of OH radicals with cyclohexane and ethane at 295 K. / Nielsen, Ole J.; Munk, Jette; Pagsberg, Palle; Sillesen, Alfred.
I: Chemical Physics Letters, Bind 128, Nr. 2, 18.07.1986, s. 168-171.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Absolute rate constants for the gas-phase reaction of OH radicals with cyclohexane and ethane at 295 K
AU - Nielsen, Ole J.
AU - Munk, Jette
AU - Pagsberg, Palle
AU - Sillesen, Alfred
PY - 1986/7/18
Y1 - 1986/7/18
N2 - The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H2O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorption around 309 nm. The rate constants were found to be k = (5.24±0.36) × 10-12 and (2.98±0.21) × 10-13 cm3 molecule-1 s-1 for cyclohexane and ethane, res- pectively. These results are compared with literature data.
AB - The absolute rate constants for the gas-phase H-atom abstraction by hydroxyl radicals from cyclohexane and ethane have been determined at room temperature. OH radicals were produced by pulse radiolysis of an H2O-Ar mixture, and the decay of OH was followed by monitoring the transient light absorption around 309 nm. The rate constants were found to be k = (5.24±0.36) × 10-12 and (2.98±0.21) × 10-13 cm3 molecule-1 s-1 for cyclohexane and ethane, res- pectively. These results are compared with literature data.
UR - http://www.scopus.com/inward/record.url?scp=0010612541&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(86)80319-0
DO - 10.1016/0009-2614(86)80319-0
M3 - Journal article
AN - SCOPUS:0010612541
VL - 128
SP - 168
EP - 171
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 2
ER -
ID: 214011572