Absolute rate constants for the reaction of CF3O2 and CF3O radicals with NO at 295 K
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
Absolute rate constants for the reaction of CF3O2 and CF3O radicals with NO at 295 K. / Sehested, Jens; Nielsen, Ole John.
I: Chemical Physics Letters, Bind 206, Nr. 1-4, 30.04.1993, s. 369-375.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - Absolute rate constants for the reaction of CF3O2 and CF3O radicals with NO at 295 K
AU - Sehested, Jens
AU - Nielsen, Ole John
PY - 1993/4/30
Y1 - 1993/4/30
N2 - Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO2 and FNO absorption transients, rate constants for reaction between CF3O and CF3O2 radicals with NO were determined, CF3O2 + NO→CF3O + NO2 (3), CF3O + NO→CF2O + FNO (5). k3 was derived to be (1.68±0.26) × 10-11 cm3 molecule-1 s-1, and k5 = (5.2±2.7) × 10-11 cm3 molecule-1, s-1. Results are discussed in the context of the atmospheric chemistry of halocarbons.
AB - Using a pulse radiolysis UV absorption technique and subsequent simulations of experimental NO2 and FNO absorption transients, rate constants for reaction between CF3O and CF3O2 radicals with NO were determined, CF3O2 + NO→CF3O + NO2 (3), CF3O + NO→CF2O + FNO (5). k3 was derived to be (1.68±0.26) × 10-11 cm3 molecule-1 s-1, and k5 = (5.2±2.7) × 10-11 cm3 molecule-1, s-1. Results are discussed in the context of the atmospheric chemistry of halocarbons.
UR - http://www.scopus.com/inward/record.url?scp=0000678944&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(93)85567-8
DO - 10.1016/0009-2614(93)85567-8
M3 - Journal article
AN - SCOPUS:0000678944
VL - 206
SP - 369
EP - 375
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 1-4
ER -
ID: 228195835