Hemicucurbit[n]urils
Publikation: Bidrag til bog/antologi/rapport › Bidrag til bog/antologi › Forskning › fagfællebedømt
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Hemicucurbit[n]urils. / Lisbjerg, Micke; Pittelkow, Michael.
Reference Module in Chemistry, Molecular Sciences and Chemical Engineering: Comprehensive Supramolecular Chemistry II. Bind 3 Elsevier, 2017. s. 221-236.Publikation: Bidrag til bog/antologi/rapport › Bidrag til bog/antologi › Forskning › fagfællebedømt
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TY - CHAP
T1 - Hemicucurbit[n]urils
AU - Lisbjerg, Micke
AU - Pittelkow, Michael
PY - 2017
Y1 - 2017
N2 - Since the discovery of the first hemicucurbit[n]uril macrocycles in 2004, a series of functional hemicucurbit[n]uril derivatives have been prepared and studies of their supramolecular chemistry have been conducted. The original hemicucurbit[n]urils (hemicucurbit[6]uril and hemicucurbit[12]uril) are only sparsely soluble, which hampered studies of their properties as potential hosts in supramolecular chemistry. Recently, a range of homologues have been synthesized (eg, the biotin[n]urils, the bambus[n]urils, and the cyclohexylhemicucurbit[n]urils) that are functionalizable and their supramolecular chemistry has been studied in a range of solvents. This has expanded the scope, and the interest in these structures is growing. In contrast to the more widely studied cucurbit[n]urils that are excellent hosts for cations, the hemicucurbit[n]urils act as hosts for anions. This article provides a comprehensive survey of the literature covering the syntheses of the homologs and derivatives, and their supramolecular chemistry
AB - Since the discovery of the first hemicucurbit[n]uril macrocycles in 2004, a series of functional hemicucurbit[n]uril derivatives have been prepared and studies of their supramolecular chemistry have been conducted. The original hemicucurbit[n]urils (hemicucurbit[6]uril and hemicucurbit[12]uril) are only sparsely soluble, which hampered studies of their properties as potential hosts in supramolecular chemistry. Recently, a range of homologues have been synthesized (eg, the biotin[n]urils, the bambus[n]urils, and the cyclohexylhemicucurbit[n]urils) that are functionalizable and their supramolecular chemistry has been studied in a range of solvents. This has expanded the scope, and the interest in these structures is growing. In contrast to the more widely studied cucurbit[n]urils that are excellent hosts for cations, the hemicucurbit[n]urils act as hosts for anions. This article provides a comprehensive survey of the literature covering the syntheses of the homologs and derivatives, and their supramolecular chemistry
U2 - 10.1016/B978-0-12-409547-2.12515-6
DO - 10.1016/B978-0-12-409547-2.12515-6
M3 - Book chapter
SN - 978-0-12-409547-2
VL - 3
SP - 221
EP - 236
BT - Reference Module in Chemistry, Molecular Sciences and Chemical Engineering
PB - Elsevier
ER -
ID: 176334729