Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry

Publikation: Bidrag til tidsskrift › Review › Forskning › fagfællebedømt

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Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry. / Mogensen, Steffen B; Taylor, Mercedes K; Lee, Ji-Woong.

I: Molecules, Bind 25, Nr. 24, 5950, 15.12.2020.

Publikation: Bidrag til tidsskrift › Review › Forskning › fagfællebedømt

Harvard

Mogensen, SB, Taylor, MK & Lee, J-W 2020, 'Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry', Molecules, bind 25, nr. 24, 5950. https://doi.org/10.3390/molecules25245950

APA

Mogensen, S. B., Taylor, M. K., & Lee, J-W. (2020). Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry. Molecules, 25(24), [5950]. https://doi.org/10.3390/molecules25245950

Vancouver

Mogensen SB, Taylor MK, Lee J-W. Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry. Molecules. 2020 dec. 15;25(24). 5950. https://doi.org/10.3390/molecules25245950

Author

Mogensen, Steffen B ; Taylor, Mercedes K ; Lee, Ji-Woong. / Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry. I: Molecules. 2020 ; Bind 25, Nr. 24.

Bibtex

@article{b4063dbc072c44aa9084423ea74a427b,
title = "Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry",
abstract = "Pyrazole, a member of the structural class of azoles, exhibits molecular properties of interest in pharmaceuticals and materials chemistry, owing to the two adjacent nitrogen atoms in the five-membered ring system. The weakly basic nitrogen atoms of deprotonated pyrazoles have been applied in coordination chemistry, particularly to access coordination polymers and metal-organic frameworks, and homocoupling reactions can in principle provide facile access to bipyrazole ligands. In this context, we summarize recent advances in homocoupling reactions of pyrazoles and other types of azoles (imidazoles, triazoles and tetrazoles) to highlight the utility of homocoupling reactions in synthesizing symmetric bi-heteroaryl systems compared with traditional synthesis. Metal-free reactions and transition-metal catalyzed homocoupling reactions are discussed with reaction mechanisms in detail.",
author = "Mogensen, {Steffen B} and Taylor, {Mercedes K} and Ji-Woong Lee",
year = "2020",
month = dec,
day = "15",
doi = "10.3390/molecules25245950",
language = "English",
volume = "25",
journal = "Molecules",
issn = "1420-3049",
publisher = "M D P I AG",
number = "24",

}

RIS

TY - JOUR

T1 - Homocoupling Reactions of Azoles and Their Applications in Coordination Chemistry

AU - Mogensen, Steffen B

AU - Taylor, Mercedes K

AU - Lee, Ji-Woong

PY - 2020/12/15

Y1 - 2020/12/15

N2 - Pyrazole, a member of the structural class of azoles, exhibits molecular properties of interest in pharmaceuticals and materials chemistry, owing to the two adjacent nitrogen atoms in the five-membered ring system. The weakly basic nitrogen atoms of deprotonated pyrazoles have been applied in coordination chemistry, particularly to access coordination polymers and metal-organic frameworks, and homocoupling reactions can in principle provide facile access to bipyrazole ligands. In this context, we summarize recent advances in homocoupling reactions of pyrazoles and other types of azoles (imidazoles, triazoles and tetrazoles) to highlight the utility of homocoupling reactions in synthesizing symmetric bi-heteroaryl systems compared with traditional synthesis. Metal-free reactions and transition-metal catalyzed homocoupling reactions are discussed with reaction mechanisms in detail.

AB - Pyrazole, a member of the structural class of azoles, exhibits molecular properties of interest in pharmaceuticals and materials chemistry, owing to the two adjacent nitrogen atoms in the five-membered ring system. The weakly basic nitrogen atoms of deprotonated pyrazoles have been applied in coordination chemistry, particularly to access coordination polymers and metal-organic frameworks, and homocoupling reactions can in principle provide facile access to bipyrazole ligands. In this context, we summarize recent advances in homocoupling reactions of pyrazoles and other types of azoles (imidazoles, triazoles and tetrazoles) to highlight the utility of homocoupling reactions in synthesizing symmetric bi-heteroaryl systems compared with traditional synthesis. Metal-free reactions and transition-metal catalyzed homocoupling reactions are discussed with reaction mechanisms in detail.

U2 - 10.3390/molecules25245950

DO - 10.3390/molecules25245950

M3 - Review

C2 - 33334079

VL - 25

JO - Molecules

JF - Molecules

SN - 1420-3049

IS - 24

M1 - 5950

ER -

ID: 254723155