A study of the DIBAL-promoted selective debenzylation of alpha-cyclodextrin protected with two different benzyl groups
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A study of the DIBAL-promoted selective debenzylation of alpha-cyclodextrin protected with two different benzyl groups. / Yousefi, Naser-Abdul; Zimmermann, Morten L.; Bols, Mikael.
I: Beilstein Journal of Organic Chemistry, Bind 18, 17.11.2022, s. 1553-1559.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - A study of the DIBAL-promoted selective debenzylation of alpha-cyclodextrin protected with two different benzyl groups
AU - Yousefi, Naser-Abdul
AU - Zimmermann, Morten L.
AU - Bols, Mikael
PY - 2022/11/17
Y1 - 2022/11/17
N2 - An alpha-cyclodextrin protected with 2,4-dichlorobenzyl groups on the primary alcohols and ordinary benzyl groups on the secondary alcohols was prepared and subjected to DIBAL (diisobutylaluminum hydride)-promoted selective debenzylation. Debenzylation proceeded by first removing two dichlorobenzyl groups from the 6A,D positions and then removing one or two benzyl groups from the 3A,D positions.
AB - An alpha-cyclodextrin protected with 2,4-dichlorobenzyl groups on the primary alcohols and ordinary benzyl groups on the secondary alcohols was prepared and subjected to DIBAL (diisobutylaluminum hydride)-promoted selective debenzylation. Debenzylation proceeded by first removing two dichlorobenzyl groups from the 6A,D positions and then removing one or two benzyl groups from the 3A,D positions.
KW - aluminum hydrides
KW - cyclodextrin
KW - debenzylation
KW - 2
KW - 4-dichlorobenzyl
KW - selective
KW - POWERFUL
KW - SUGARS
U2 - 10.3762/bjoc.18.165
DO - 10.3762/bjoc.18.165
M3 - Journal article
C2 - 36474968
VL - 18
SP - 1553
EP - 1559
JO - Beilstein Journal of Organic Chemistry
JF - Beilstein Journal of Organic Chemistry
SN - 2195-951X
ER -
ID: 327696977