Absolute and relative rate constants for the gas-phase reaction of OH radicals with CH3NO2, CD3NO2 and CH3CH2CH3 at 295 K and 1 ATM
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Absolute and relative rate constants for the gas-phase reaction of OH radicals with CH3NO2, CD3NO2 and CH3CH2CH3 at 295 K and 1 ATM. / Nielsen, Ole J.; Sidebottom, Howard W.; O'Farrell, Denis J.; Donlon, Michael; Treacy, Jack.
I: Chemical Physics Letters, Bind 146, Nr. 3-4, 06.05.1988, s. 197-203.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Absolute and relative rate constants for the gas-phase reaction of OH radicals with CH3NO2, CD3NO2 and CH3CH2CH3 at 295 K and 1 ATM
AU - Nielsen, Ole J.
AU - Sidebottom, Howard W.
AU - O'Farrell, Denis J.
AU - Donlon, Michael
AU - Treacy, Jack
PY - 1988/5/6
Y1 - 1988/5/6
N2 - The rate constants for the gas-phase reaction of OH radicals with nitromethane, deutero-nitromethane and propane have been determined at 295 ± 2 K and a total pressure of approximately 1 atm; a photolytic relative technique and an absolute method were applied. Methyl nitrite was used as the OH source in the relative method. In the absolute technique, pulse radiolysis was combined with kinetic spectroscopy. H2O-Ar mixtures were irradiated and the OH kinetics recorded by following the transient light absorption around 309 nm. The results are compared with literature data.
AB - The rate constants for the gas-phase reaction of OH radicals with nitromethane, deutero-nitromethane and propane have been determined at 295 ± 2 K and a total pressure of approximately 1 atm; a photolytic relative technique and an absolute method were applied. Methyl nitrite was used as the OH source in the relative method. In the absolute technique, pulse radiolysis was combined with kinetic spectroscopy. H2O-Ar mixtures were irradiated and the OH kinetics recorded by following the transient light absorption around 309 nm. The results are compared with literature data.
UR - http://www.scopus.com/inward/record.url?scp=33646915479&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(88)87430-X
DO - 10.1016/0009-2614(88)87430-X
M3 - Journal article
AN - SCOPUS:33646915479
VL - 146
SP - 197
EP - 203
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 3-4
ER -
ID: 214272524