Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Standard

Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2. / Sehested, Jens; Christensen, Lene Krogh; Møgelberg, Trine; Nielsen, Ole J.; Wallington, Timothy J.; Guschin, Andrei; Orlando, John J.; Tyndall, Geoffrey S.

I: Journal of Physical Chemistry A, Bind 102, Nr. 10, 05.03.1998, s. 1779-1789.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Sehested, J, Christensen, LK, Møgelberg, T, Nielsen, OJ, Wallington, TJ, Guschin, A, Orlando, JJ & Tyndall, GS 1998, 'Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2', Journal of Physical Chemistry A, bind 102, nr. 10, s. 1779-1789.

APA

Sehested, J., Christensen, L. K., Møgelberg, T., Nielsen, O. J., Wallington, T. J., Guschin, A., Orlando, J. J., & Tyndall, G. S. (1998). Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2. Journal of Physical Chemistry A, 102(10), 1779-1789.

Vancouver

Sehested J, Christensen LK, Møgelberg T, Nielsen OJ, Wallington TJ, Guschin A o.a. Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2. Journal of Physical Chemistry A. 1998 mar. 5;102(10):1779-1789.

Author

Sehested, Jens ; Christensen, Lene Krogh ; Møgelberg, Trine ; Nielsen, Ole J. ; Wallington, Timothy J. ; Guschin, Andrei ; Orlando, John J. ; Tyndall, Geoffrey S. / Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2. I: Journal of Physical Chemistry A. 1998 ; Bind 102, Nr. 10. s. 1779-1789.

Bibtex

@article{c1e09e6376ff4f9a94426fa6d71e1726,
title = "Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2",
abstract = "A pulse-radiolysis system was used to measure absolute rate constants for the reactions of CH3C(O)O2 radicals with NO and NO2 at 295 K and 1000 mbar total pressure of SF6. When the rate of formation and decay of NO2 using its absorption at 400.5 and 452 nm were monitored, the rate constants k(CH3C(O)O2 + NO) = (2.0 ± 0.3) × 10-11 and k(CH3C(O)O2 + NO2) = (1.0 ± 0.2) × 10-11 cm3 molecule-1 s-1 were determined. Long path-length Fourier transform infrared spectrometers were used to study the rate-constant ratio k(CH3C-(O)O2 + NO)/k(CH3C(O)O2 + NO2) in 6-700 Torr total pressure of N2 diluent at 243-295 K. At 295 K in 700 Torr of N2 diluent k(CH3C(O)O2 + NO)/k(CH3C(O)O2 + NO2) = 2.07 ± 0.21. The results are discussed in the context of the atmospheric chemistry of acetylperoxy radicals.",
author = "Jens Sehested and Christensen, {Lene Krogh} and Trine M{\o}gelberg and Nielsen, {Ole J.} and Wallington, {Timothy J.} and Andrei Guschin and Orlando, {John J.} and Tyndall, {Geoffrey S.}",
year = "1998",
month = mar,
day = "5",
language = "English",
volume = "102",
pages = "1779--1789",
journal = "Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory",
issn = "1089-5639",
publisher = "American Chemical Society",
number = "10",

}

RIS

TY - JOUR

T1 - Absolute and relative rate constants for the reactions CH3C(O)O2 + NO and CH3C(O)O2 + NO2 and thermal stability of CH3C(O)O2NO2

AU - Sehested, Jens

AU - Christensen, Lene Krogh

AU - Møgelberg, Trine

AU - Nielsen, Ole J.

AU - Wallington, Timothy J.

AU - Guschin, Andrei

AU - Orlando, John J.

AU - Tyndall, Geoffrey S.

PY - 1998/3/5

Y1 - 1998/3/5

N2 - A pulse-radiolysis system was used to measure absolute rate constants for the reactions of CH3C(O)O2 radicals with NO and NO2 at 295 K and 1000 mbar total pressure of SF6. When the rate of formation and decay of NO2 using its absorption at 400.5 and 452 nm were monitored, the rate constants k(CH3C(O)O2 + NO) = (2.0 ± 0.3) × 10-11 and k(CH3C(O)O2 + NO2) = (1.0 ± 0.2) × 10-11 cm3 molecule-1 s-1 were determined. Long path-length Fourier transform infrared spectrometers were used to study the rate-constant ratio k(CH3C-(O)O2 + NO)/k(CH3C(O)O2 + NO2) in 6-700 Torr total pressure of N2 diluent at 243-295 K. At 295 K in 700 Torr of N2 diluent k(CH3C(O)O2 + NO)/k(CH3C(O)O2 + NO2) = 2.07 ± 0.21. The results are discussed in the context of the atmospheric chemistry of acetylperoxy radicals.

AB - A pulse-radiolysis system was used to measure absolute rate constants for the reactions of CH3C(O)O2 radicals with NO and NO2 at 295 K and 1000 mbar total pressure of SF6. When the rate of formation and decay of NO2 using its absorption at 400.5 and 452 nm were monitored, the rate constants k(CH3C(O)O2 + NO) = (2.0 ± 0.3) × 10-11 and k(CH3C(O)O2 + NO2) = (1.0 ± 0.2) × 10-11 cm3 molecule-1 s-1 were determined. Long path-length Fourier transform infrared spectrometers were used to study the rate-constant ratio k(CH3C-(O)O2 + NO)/k(CH3C(O)O2 + NO2) in 6-700 Torr total pressure of N2 diluent at 243-295 K. At 295 K in 700 Torr of N2 diluent k(CH3C(O)O2 + NO)/k(CH3C(O)O2 + NO2) = 2.07 ± 0.21. The results are discussed in the context of the atmospheric chemistry of acetylperoxy radicals.

UR - http://www.scopus.com/inward/record.url?scp=0001328916&partnerID=8YFLogxK

M3 - Journal article

AN - SCOPUS:0001328916

VL - 102

SP - 1779

EP - 1789

JO - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

JF - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

SN - 1089-5639

IS - 10

ER -

ID: 225753859