Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K

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Standard

Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K. / Nelson, Linda; Rattigan, Oliver; Neavyn, Ruaidhri; Sidebottom, Howard; Treacy, Jack; Nielsen, Ole John.

I: International Journal of Chemical Kinetics, Bind 22, Nr. 11, 01.01.1990, s. 1111-1126.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Nelson, L, Rattigan, O, Neavyn, R, Sidebottom, H, Treacy, J & Nielsen, OJ 1990, 'Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K', International Journal of Chemical Kinetics, bind 22, nr. 11, s. 1111-1126. https://doi.org/10.1002/kin.550221102

APA

Nelson, L., Rattigan, O., Neavyn, R., Sidebottom, H., Treacy, J., & Nielsen, O. J. (1990). Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K. International Journal of Chemical Kinetics, 22(11), 1111-1126. https://doi.org/10.1002/kin.550221102

Vancouver

Nelson L, Rattigan O, Neavyn R, Sidebottom H, Treacy J, Nielsen OJ. Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K. International Journal of Chemical Kinetics. 1990 jan. 1;22(11):1111-1126. https://doi.org/10.1002/kin.550221102

Author

Nelson, Linda ; Rattigan, Oliver ; Neavyn, Ruaidhri ; Sidebottom, Howard ; Treacy, Jack ; Nielsen, Ole John. / Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K. I: International Journal of Chemical Kinetics. 1990 ; Bind 22, Nr. 11. s. 1111-1126.

Bibtex

@article{d17f00061e144de4acd8a302dbcef189,
title = "Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K",
abstract = "Rate constants for the gas‐phase reactions of hydroxyl radicals and chlorine atoms with aliphatic alcohols and ethers have been determined at 298 ± 2 K and at a total pressure of 1 atmosphere. The OH radical rate data were obtained using both the absolute technique of pulse radiolysis combined with kinetic UV spectroscopy and a conventional photolytic relative rate method. The Cl atom rate constants were measured using only the relative rate method. Values of the rate constants in units of 10−12 cm3 molecule−1 s−1 are: (Formula Presented.) The above relative rate constants are based on the values of 퓀(OH + c‐C6H12) = 7.49 × 10−12 cm3 molecule−1 s−1 and 퓀(Cl + c‐C6H12) = 311 × 10−12 cm3 molecule−1 s−1. Attempts to corre late the trends in the rate constant data in terms of the bond dissociation energies and inductive effects are discussed.",
author = "Linda Nelson and Oliver Rattigan and Ruaidhri Neavyn and Howard Sidebottom and Jack Treacy and Nielsen, {Ole John}",
year = "1990",
month = jan,
day = "1",
doi = "10.1002/kin.550221102",
language = "English",
volume = "22",
pages = "1111--1126",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "JohnWiley & Sons, Inc.",
number = "11",

}

RIS

TY - JOUR

T1 - Absolute and relative rate constants for the reactions of hydroxyl radicals and chlorine atoms with a series of aliphatic alcohols and ethers at 298 K

AU - Nelson, Linda

AU - Rattigan, Oliver

AU - Neavyn, Ruaidhri

AU - Sidebottom, Howard

AU - Treacy, Jack

AU - Nielsen, Ole John

PY - 1990/1/1

Y1 - 1990/1/1

N2 - Rate constants for the gas‐phase reactions of hydroxyl radicals and chlorine atoms with aliphatic alcohols and ethers have been determined at 298 ± 2 K and at a total pressure of 1 atmosphere. The OH radical rate data were obtained using both the absolute technique of pulse radiolysis combined with kinetic UV spectroscopy and a conventional photolytic relative rate method. The Cl atom rate constants were measured using only the relative rate method. Values of the rate constants in units of 10−12 cm3 molecule−1 s−1 are: (Formula Presented.) The above relative rate constants are based on the values of 퓀(OH + c‐C6H12) = 7.49 × 10−12 cm3 molecule−1 s−1 and 퓀(Cl + c‐C6H12) = 311 × 10−12 cm3 molecule−1 s−1. Attempts to corre late the trends in the rate constant data in terms of the bond dissociation energies and inductive effects are discussed.

AB - Rate constants for the gas‐phase reactions of hydroxyl radicals and chlorine atoms with aliphatic alcohols and ethers have been determined at 298 ± 2 K and at a total pressure of 1 atmosphere. The OH radical rate data were obtained using both the absolute technique of pulse radiolysis combined with kinetic UV spectroscopy and a conventional photolytic relative rate method. The Cl atom rate constants were measured using only the relative rate method. Values of the rate constants in units of 10−12 cm3 molecule−1 s−1 are: (Formula Presented.) The above relative rate constants are based on the values of 퓀(OH + c‐C6H12) = 7.49 × 10−12 cm3 molecule−1 s−1 and 퓀(Cl + c‐C6H12) = 311 × 10−12 cm3 molecule−1 s−1. Attempts to corre late the trends in the rate constant data in terms of the bond dissociation energies and inductive effects are discussed.

UR - http://www.scopus.com/inward/record.url?scp=0025509979&partnerID=8YFLogxK

U2 - 10.1002/kin.550221102

DO - 10.1002/kin.550221102

M3 - Journal article

AN - SCOPUS:0025509979

VL - 22

SP - 1111

EP - 1126

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 11

ER -

ID: 214272873