Absolute rate constants for the reaction of NO with a series of peroxy radicals in the gas phase at 295 K
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Absolute rate constants for the reaction of NO with a series of peroxy radicals in the gas phase at 295 K. / Sehested, Jens; Nielsen, Ole John; Wallington, Timothy J.
I: Chemical Physics Letters, Bind 213, Nr. 5-6, 15.10.1993, s. 457-464.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Absolute rate constants for the reaction of NO with a series of peroxy radicals in the gas phase at 295 K
AU - Sehested, Jens
AU - Nielsen, Ole John
AU - Wallington, Timothy J.
PY - 1993/10/15
Y1 - 1993/10/15
N2 - The rate constants for the reaction of NO with a series of peroxy radicals: CH3O2, C2H5O2, (CH3)3CCH2O2, (CH3)3CC(CH3)2CH2 O2, CH2FO2, CH2ClO2, CH2BrO2, CHF2O2, CF2ClO2, CHF2CF2O2, CF3CF2O2, CFCl2CH2O2 and CF2ClCH2O2 were measured at 298 K and a total pressure of 1 atm. The rate constants were obtained using the absolute technique of pulse radiolysis combined with time-resolved UVVIS spectroscopy. The results are discussed in terms of reactivity trends and the atmospheric chemistry of peroxy radicals.
AB - The rate constants for the reaction of NO with a series of peroxy radicals: CH3O2, C2H5O2, (CH3)3CCH2O2, (CH3)3CC(CH3)2CH2 O2, CH2FO2, CH2ClO2, CH2BrO2, CHF2O2, CF2ClO2, CHF2CF2O2, CF3CF2O2, CFCl2CH2O2 and CF2ClCH2O2 were measured at 298 K and a total pressure of 1 atm. The rate constants were obtained using the absolute technique of pulse radiolysis combined with time-resolved UVVIS spectroscopy. The results are discussed in terms of reactivity trends and the atmospheric chemistry of peroxy radicals.
UR - http://www.scopus.com/inward/record.url?scp=4244009285&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(93)89142-5
DO - 10.1016/0009-2614(93)89142-5
M3 - Journal article
AN - SCOPUS:4244009285
VL - 213
SP - 457
EP - 464
JO - Chemical Physics Letters
JF - Chemical Physics Letters
SN - 0009-2614
IS - 5-6
ER -
ID: 228194951