An absolute and relative rate study of the reaction of oh radicals with dimethyl sulfide
Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Standard
An absolute and relative rate study of the reaction of oh radicals with dimethyl sulfide. / Nielsen, Ole J.; Sidebottom, Howard W.; Nelson, Linda; Treacy, Jack J.; O'farrell, Denis J.
I: International Journal of Chemical Kinetics, Bind 21, Nr. 12, 01.01.1989, s. 1101-1112.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
Harvard
APA
Vancouver
Author
Bibtex
}
RIS
TY - JOUR
T1 - An absolute and relative rate study of the reaction of oh radicals with dimethyl sulfide
AU - Nielsen, Ole J.
AU - Sidebottom, Howard W.
AU - Nelson, Linda
AU - Treacy, Jack J.
AU - O'farrell, Denis J.
PY - 1989/1/1
Y1 - 1989/1/1
N2 - The gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3, DMS) has been studied using both an absolute and a relative technique at 295 ± 2 K and a total pressure of 1 atm. The absolute rate technique of pulse radiolysis combined with kinetic spectroscopy was applied. Using this technique a rate constant of (3.5 ± 0.2) × 10−12 cm3 molecule−1 s−1 was obtained. For the relative rate method, rate constants for the reaction of OH with DMS were found to increase with increasing concentrations of added NO. These results are compared with the large body of kinetic and mechanistic data previously reported in the literature.
AB - The gas phase reaction of OH radicals with dimethyl sulfide (CH3SCH3, DMS) has been studied using both an absolute and a relative technique at 295 ± 2 K and a total pressure of 1 atm. The absolute rate technique of pulse radiolysis combined with kinetic spectroscopy was applied. Using this technique a rate constant of (3.5 ± 0.2) × 10−12 cm3 molecule−1 s−1 was obtained. For the relative rate method, rate constants for the reaction of OH with DMS were found to increase with increasing concentrations of added NO. These results are compared with the large body of kinetic and mechanistic data previously reported in the literature.
UR - http://www.scopus.com/inward/record.url?scp=0024932217&partnerID=8YFLogxK
U2 - 10.1002/kin.550211203
DO - 10.1002/kin.550211203
M3 - Journal article
AN - SCOPUS:0024932217
VL - 21
SP - 1101
EP - 1112
JO - International Journal of Chemical Kinetics
JF - International Journal of Chemical Kinetics
SN - 0538-8066
IS - 12
ER -
ID: 214272751