A pulse radiolysis technique was used to investigate the kinetics and products of the reaction of CF₂BrH with fluorine atoms at 296 K. This reaction forms an adduct which is in dynamic equilibrium with CF₂BrH and fluorine atoms. The UV absorption spectrum of the adduct was measured relative to the UV spectrum of the CH₃O₂ radical over the range 230-380 nm. At 280 nm, an absorption cross section of (1.3 ± 0.3) × 10^-17 cm² molecule^-1 was determined. From the absorption at 280 nm the equilibrium constant K₅ = [adduct]/ ([F][CF₂BrH]) was measured to be (1.59 ± 0.13) × 10^-17 cm³ molecule^-1. In 1 atm of SF₆, the forward rate constant k₅ = (1.4 ± 0.5) × 10^-11 cm³ molecule^-1 s^-1 and the backward rate constant k_-5 = (8.8 ± 3.0) × 10⁵ s^-1 were determined by monitoring the rate of formation and loss of the adduct. As part of the present work a relative rate technique was used to measure k(Cl+CF₂BrH) = (5.8 ± 1.0) × 10^-15 cm³ molecule^-1 s^-1 at 296 K and 700 Torr of N₂. The fate of the oxy radical, CF₂BrO, in the atmosphere is bromine atom elimination and formation of COF₂.