Atmospheric chemistry of FCOx radicals: Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction

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Standard

Atmospheric chemistry of FCOx radicals : Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction. / Wallington, Timothy J.; Schneider, William F.; Møgelberg, Trine E.; Nielsen, Ole J.; Sehested, Jens.

I: International Journal of Chemical Kinetics, Bind 27, Nr. 4, 01.01.1995, s. 391-402.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Wallington, TJ, Schneider, WF, Møgelberg, TE, Nielsen, OJ & Sehested, J 1995, 'Atmospheric chemistry of FCOx radicals: Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction', International Journal of Chemical Kinetics, bind 27, nr. 4, s. 391-402. https://doi.org/10.1002/kin.550270410

APA

Wallington, T. J., Schneider, W. F., Møgelberg, T. E., Nielsen, O. J., & Sehested, J. (1995). Atmospheric chemistry of FCOx radicals: Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction. International Journal of Chemical Kinetics, 27(4), 391-402. https://doi.org/10.1002/kin.550270410

Vancouver

Wallington TJ, Schneider WF, Møgelberg TE, Nielsen OJ, Sehested J. Atmospheric chemistry of FCOx radicals: Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction. International Journal of Chemical Kinetics. 1995 jan. 1;27(4):391-402. https://doi.org/10.1002/kin.550270410

Author

Wallington, Timothy J. ; Schneider, William F. ; Møgelberg, Trine E. ; Nielsen, Ole J. ; Sehested, Jens. / Atmospheric chemistry of FCOx radicals : Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction. I: International Journal of Chemical Kinetics. 1995 ; Bind 27, Nr. 4. s. 391-402.

Bibtex

@article{480481d6e87d487c90f0a62737032ec9,
title = "Atmospheric chemistry of FCOx radicals: Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction",
abstract = "A pulse radiolysis system was used to study the kinetics of the reaction of FC(O)O2 radicals with NO2. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ± 0.6) × 10−12 cm3 molecule−1 s−1 at 296 K and 500–1000 mbar pressure of SF6 diluent. A long path length Fourier transform infrared spectrometer was used to investigate the thermal stability of the product FC(O)O2NO2. The rate of thermal decomposition of FC(O)O2NO2 was independent of the total pressure of N2 diluent over the range 100–700 torr and was fit by the expression k−3 = 6.0 × 1016 exp(−14150/T) s−1. The results are discussed in the context of the atmospheric chemistry of FCOx radicals. {\textcopyright} 1995 John Wiley & Sons, Inc.",
author = "Wallington, {Timothy J.} and Schneider, {William F.} and M{\o}gelberg, {Trine E.} and Nielsen, {Ole J.} and Jens Sehested",
year = "1995",
month = jan,
day = "1",
doi = "10.1002/kin.550270410",
language = "English",
volume = "27",
pages = "391--402",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "JohnWiley & Sons, Inc.",
number = "4",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of FCOx radicals

T2 - Kinetic and mechanistic study of the FC(O)O2 + NO2 reaction

AU - Wallington, Timothy J.

AU - Schneider, William F.

AU - Møgelberg, Trine E.

AU - Nielsen, Ole J.

AU - Sehested, Jens

PY - 1995/1/1

Y1 - 1995/1/1

N2 - A pulse radiolysis system was used to study the kinetics of the reaction of FC(O)O2 radicals with NO2. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ± 0.6) × 10−12 cm3 molecule−1 s−1 at 296 K and 500–1000 mbar pressure of SF6 diluent. A long path length Fourier transform infrared spectrometer was used to investigate the thermal stability of the product FC(O)O2NO2. The rate of thermal decomposition of FC(O)O2NO2 was independent of the total pressure of N2 diluent over the range 100–700 torr and was fit by the expression k−3 = 6.0 × 1016 exp(−14150/T) s−1. The results are discussed in the context of the atmospheric chemistry of FCOx radicals. © 1995 John Wiley & Sons, Inc.

AB - A pulse radiolysis system was used to study the kinetics of the reaction of FC(O)O2 radicals with NO2. By monitoring the rate of the decay of NO2 using its absorption at 400 nm the reaction rate constant was determined to be (5.5 ± 0.6) × 10−12 cm3 molecule−1 s−1 at 296 K and 500–1000 mbar pressure of SF6 diluent. A long path length Fourier transform infrared spectrometer was used to investigate the thermal stability of the product FC(O)O2NO2. The rate of thermal decomposition of FC(O)O2NO2 was independent of the total pressure of N2 diluent over the range 100–700 torr and was fit by the expression k−3 = 6.0 × 1016 exp(−14150/T) s−1. The results are discussed in the context of the atmospheric chemistry of FCOx radicals. © 1995 John Wiley & Sons, Inc.

UR - http://www.scopus.com/inward/record.url?scp=84980294994&partnerID=8YFLogxK

U2 - 10.1002/kin.550270410

DO - 10.1002/kin.550270410

M3 - Journal article

AN - SCOPUS:84980294994

VL - 27

SP - 391

EP - 402

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 4

ER -

ID: 225753337