Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K

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Standard

Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K. / Sehested, J.; Sehested, K.; Nielsen, O. J.; Wallington, T. J.

I: Journal of Physical Chemistry, Bind 98, Nr. 27, 01.01.1994, s. 6731-6739.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Sehested, J, Sehested, K, Nielsen, OJ & Wallington, TJ 1994, 'Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K', Journal of Physical Chemistry, bind 98, nr. 27, s. 6731-6739. https://doi.org/10.1021/j100078a014

APA

Sehested, J., Sehested, K., Nielsen, O. J., & Wallington, T. J. (1994). Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K. Journal of Physical Chemistry, 98(27), 6731-6739. https://doi.org/10.1021/j100078a014

Vancouver

Sehested J, Sehested K, Nielsen OJ, Wallington TJ. Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K. Journal of Physical Chemistry. 1994 jan. 1;98(27):6731-6739. https://doi.org/10.1021/j100078a014

Author

Sehested, J. ; Sehested, K. ; Nielsen, O. J. ; Wallington, T. J. / Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K. I: Journal of Physical Chemistry. 1994 ; Bind 98, Nr. 27. s. 6731-6739.

Bibtex

@article{65dcdf0d7f7947d0bee78502da69aed0,
title = "Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K",
abstract = "Using pulse radiolysis combined with UV absorption spectroscopy, upper limits for the rate constants of the reaction of the FO2 radical with O3, CH4, and CO were determined to be <3.4 × 10-16, <4.1 × 10-15, and <5.1 × 10-16 cm3 molecule-1 s-1, respectively. The rate constants for the reactions of FO2 radicals with NO and NO2 were measured: FO2 + NO → FNO + O2 (10a); FO2 + NO2 → products (11). The rate constants for reactions 10 and 11 were determined to be (1.47 ± 0.08) × 10-12 and (1.05 ± 0.15) × 10-13 cm3 molecule-1 s-1, respectively. Reaction 10a was found to give FNO in a yield of 100 ± 14%. As a part of this work, an upper limit of the reaction of FO radicals with O3 was determined to be <1.2 × 10-12 cm3 molecule-1 s-1. Results are discussed in the context of the atmospheric chemistry of the FO2 radical and hydrofluorocarbons.",
author = "J. Sehested and K. Sehested and Nielsen, {O. J.} and Wallington, {T. J.}",
year = "1994",
month = jan,
day = "1",
doi = "10.1021/j100078a014",
language = "English",
volume = "98",
pages = "6731--6739",
journal = "Journal of Physical Chemistry",
issn = "0022-3654",
publisher = "American Chemical Society",
number = "27",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of FO2 radicals. Reaction with Ch4, O3, No, No2, and Co at 295 K

AU - Sehested, J.

AU - Sehested, K.

AU - Nielsen, O. J.

AU - Wallington, T. J.

PY - 1994/1/1

Y1 - 1994/1/1

N2 - Using pulse radiolysis combined with UV absorption spectroscopy, upper limits for the rate constants of the reaction of the FO2 radical with O3, CH4, and CO were determined to be <3.4 × 10-16, <4.1 × 10-15, and <5.1 × 10-16 cm3 molecule-1 s-1, respectively. The rate constants for the reactions of FO2 radicals with NO and NO2 were measured: FO2 + NO → FNO + O2 (10a); FO2 + NO2 → products (11). The rate constants for reactions 10 and 11 were determined to be (1.47 ± 0.08) × 10-12 and (1.05 ± 0.15) × 10-13 cm3 molecule-1 s-1, respectively. Reaction 10a was found to give FNO in a yield of 100 ± 14%. As a part of this work, an upper limit of the reaction of FO radicals with O3 was determined to be <1.2 × 10-12 cm3 molecule-1 s-1. Results are discussed in the context of the atmospheric chemistry of the FO2 radical and hydrofluorocarbons.

AB - Using pulse radiolysis combined with UV absorption spectroscopy, upper limits for the rate constants of the reaction of the FO2 radical with O3, CH4, and CO were determined to be <3.4 × 10-16, <4.1 × 10-15, and <5.1 × 10-16 cm3 molecule-1 s-1, respectively. The rate constants for the reactions of FO2 radicals with NO and NO2 were measured: FO2 + NO → FNO + O2 (10a); FO2 + NO2 → products (11). The rate constants for reactions 10 and 11 were determined to be (1.47 ± 0.08) × 10-12 and (1.05 ± 0.15) × 10-13 cm3 molecule-1 s-1, respectively. Reaction 10a was found to give FNO in a yield of 100 ± 14%. As a part of this work, an upper limit of the reaction of FO radicals with O3 was determined to be <1.2 × 10-12 cm3 molecule-1 s-1. Results are discussed in the context of the atmospheric chemistry of the FO2 radical and hydrofluorocarbons.

UR - http://www.scopus.com/inward/record.url?scp=0028767568&partnerID=8YFLogxK

U2 - 10.1021/j100078a014

DO - 10.1021/j100078a014

M3 - Journal article

AN - SCOPUS:0028767568

VL - 98

SP - 6731

EP - 6739

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

SN - 0022-3654

IS - 27

ER -

ID: 228193375