Atmospheric chemistry of HFC-134a: Kinetics of the decomposition of the alkoxy radical CF3CFHO

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Standard

Atmospheric chemistry of HFC-134a : Kinetics of the decomposition of the alkoxy radical CF3CFHO. / Møgelberg, Trine E.; Sehested, Jens; Wallington, Timothy J.; Nielsen, Ole J.

I: International Journal of Chemical Kinetics, Bind 29, Nr. 3, 01.01.1997, s. 209-217.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Møgelberg, TE, Sehested, J, Wallington, TJ & Nielsen, OJ 1997, 'Atmospheric chemistry of HFC-134a: Kinetics of the decomposition of the alkoxy radical CF3CFHO', International Journal of Chemical Kinetics, bind 29, nr. 3, s. 209-217. https://doi.org/10.1002/(SICI)1097-4601(1997)29:3<209::AID-KIN8>3.0.CO;2-Y

APA

Møgelberg, T. E., Sehested, J., Wallington, T. J., & Nielsen, O. J. (1997). Atmospheric chemistry of HFC-134a: Kinetics of the decomposition of the alkoxy radical CF3CFHO. International Journal of Chemical Kinetics, 29(3), 209-217. https://doi.org/10.1002/(SICI)1097-4601(1997)29:3<209::AID-KIN8>3.0.CO;2-Y

Vancouver

Møgelberg TE, Sehested J, Wallington TJ, Nielsen OJ. Atmospheric chemistry of HFC-134a: Kinetics of the decomposition of the alkoxy radical CF3CFHO. International Journal of Chemical Kinetics. 1997 jan. 1;29(3):209-217. https://doi.org/10.1002/(SICI)1097-4601(1997)29:3<209::AID-KIN8>3.0.CO;2-Y

Author

Møgelberg, Trine E. ; Sehested, Jens ; Wallington, Timothy J. ; Nielsen, Ole J. / Atmospheric chemistry of HFC-134a : Kinetics of the decomposition of the alkoxy radical CF3CFHO. I: International Journal of Chemical Kinetics. 1997 ; Bind 29, Nr. 3. s. 209-217.

Bibtex

@article{9eb829ab4d924a9d80c739ab18050986,
title = "Atmospheric chemistry of HFC-134a: Kinetics of the decomposition of the alkoxy radical CF3CFHO",
abstract = "Decomposition of the CF3CFHO radical formed in the reaction of CF3CFHO2 radicals with NO was studied at 296 and 393 K using a pulse radiolysis transient VIS-UV absorption absolute rate technique. At room temperature in 1 atmosphere of SF6 diluent it was found that the majority (79 ′ 20)% of CF3CFHO radicals formed in the CF3CFHO2 + NO reaction decompose within 3 μs via C - C bond scission. This result is discussed with respect to the current understanding of the atmospheric degradation of HFC-134a. As a part of the present work the rate constant ratio kCF3CFH+02/kCFSCFH+NO was determined to be 0.144 ′ 0.029 in one atmosphere of SF6 diluent at 296 K.",
author = "M{\o}gelberg, {Trine E.} and Jens Sehested and Wallington, {Timothy J.} and Nielsen, {Ole J.}",
year = "1997",
month = jan,
day = "1",
doi = "10.1002/(SICI)1097-4601(1997)29:3<209::AID-KIN8>3.0.CO;2-Y",
language = "English",
volume = "29",
pages = "209--217",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "JohnWiley & Sons, Inc.",
number = "3",

}

RIS

TY - JOUR

T1 - Atmospheric chemistry of HFC-134a

T2 - Kinetics of the decomposition of the alkoxy radical CF3CFHO

AU - Møgelberg, Trine E.

AU - Sehested, Jens

AU - Wallington, Timothy J.

AU - Nielsen, Ole J.

PY - 1997/1/1

Y1 - 1997/1/1

N2 - Decomposition of the CF3CFHO radical formed in the reaction of CF3CFHO2 radicals with NO was studied at 296 and 393 K using a pulse radiolysis transient VIS-UV absorption absolute rate technique. At room temperature in 1 atmosphere of SF6 diluent it was found that the majority (79 ′ 20)% of CF3CFHO radicals formed in the CF3CFHO2 + NO reaction decompose within 3 μs via C - C bond scission. This result is discussed with respect to the current understanding of the atmospheric degradation of HFC-134a. As a part of the present work the rate constant ratio kCF3CFH+02/kCFSCFH+NO was determined to be 0.144 ′ 0.029 in one atmosphere of SF6 diluent at 296 K.

AB - Decomposition of the CF3CFHO radical formed in the reaction of CF3CFHO2 radicals with NO was studied at 296 and 393 K using a pulse radiolysis transient VIS-UV absorption absolute rate technique. At room temperature in 1 atmosphere of SF6 diluent it was found that the majority (79 ′ 20)% of CF3CFHO radicals formed in the CF3CFHO2 + NO reaction decompose within 3 μs via C - C bond scission. This result is discussed with respect to the current understanding of the atmospheric degradation of HFC-134a. As a part of the present work the rate constant ratio kCF3CFH+02/kCFSCFH+NO was determined to be 0.144 ′ 0.029 in one atmosphere of SF6 diluent at 296 K.

UR - http://www.scopus.com/inward/record.url?scp=0031104484&partnerID=8YFLogxK

U2 - 10.1002/(SICI)1097-4601(1997)29:3<209::AID-KIN8>3.0.CO;2-Y

DO - 10.1002/(SICI)1097-4601(1997)29:3<209::AID-KIN8>3.0.CO;2-Y

M3 - Journal article

AN - SCOPUS:0031104484

VL - 29

SP - 209

EP - 217

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 3

ER -

ID: 214271760