Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1)

Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 - x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system

Publikation: Bidrag til tidsskrift › Letter › Forskning › fagfællebedømt

Jamie L. Manson
John A. Schlueter
Kerry E. Garrett
Paul A. Goddard
Tom Lancaster
Johannes S. Möller
Stephen J. Blundell
Andrew J. Steele
Isabel Franke
Francis L. Pratt
John Singleton
Bendix, Jesper
Saul H. Lapidus
Marc Uhlarz
Oscar Ayala-Valenzuela
Ross D. McDonald
Mary Gurak
Christopher Baines

The title compounds are bimetallic MOFs containing [Cu(pyz)₂]²⁺ square lattices linked by MF₆ ^n- octahedra. In each, only the Cu²⁺ spins exhibit long-range magnetic order below 3.5 K (M = V⁴⁺) and 2.6 K (M = Ga³⁺). The V⁴⁺ spins remain disordered down to 0.5 K.

Originalsprog	Engelsk
Tidsskrift	Chemical Communications
Vol/bind	52
Udgave nummer	85
Sider (fra-til)	12653-12656
Antal sider	4
ISSN	1359-7345
DOI	https://doi.org/10.1039/c6cc05873f
Status	Udgivet - 2016

ID: 169728412

Kemisk Institut

Bimetallic MOFs (H3O)x[Cu(MF6)(pyrazine)2]·(4 - x)H2O (M = V4+, x = 0; M = Ga3+, x = 1): co-existence of ordered and disordered quantum spins in the V4+ system

Bimetallic MOFs (H₃O)_x[Cu(MF₆)(pyrazine)₂]·(4 - x)H₂O (M = V⁴⁺, x = 0; M = Ga³⁺, x = 1): co-existence of ordered and disordered quantum spins in the V⁴⁺ system