Controlling the optical properties of boron subphthalocyanines and their analogues

Publikation: Bidrag til tidsskrift › Review › Forskning › fagfællebedømt

Standard

Controlling the optical properties of boron subphthalocyanines and their analogues. / Dowds, Mathias; Nielsen, Mogens Brøndsted.

I: Molecular Systems Design and Engineering, Bind 6, 2021, s. 6-24.

Publikation: Bidrag til tidsskrift › Review › Forskning › fagfællebedømt

Harvard

Dowds, M & Nielsen, MB 2021, 'Controlling the optical properties of boron subphthalocyanines and their analogues', Molecular Systems Design and Engineering, bind 6, s. 6-24. https://doi.org/10.1039/d0me00150c

APA

Dowds, M., & Nielsen, M. B. (2021). Controlling the optical properties of boron subphthalocyanines and their analogues. Molecular Systems Design and Engineering, 6, 6-24. https://doi.org/10.1039/d0me00150c

Vancouver

Dowds M, Nielsen MB. Controlling the optical properties of boron subphthalocyanines and their analogues. Molecular Systems Design and Engineering. 2021;6:6-24. https://doi.org/10.1039/d0me00150c

Author

Dowds, Mathias ; Nielsen, Mogens Brøndsted. / Controlling the optical properties of boron subphthalocyanines and their analogues. I: Molecular Systems Design and Engineering. 2021 ; Bind 6. s. 6-24.

Bibtex

@article{8350b79cc2d2464e8c42ea0c6140a13e,
title = "Controlling the optical properties of boron subphthalocyanines and their analogues",
abstract = "Boron subphthalocyanines (SubPcs) are cone shaped π-conjugated molecules comprised of three azomethine-bridged isoindole units and a central boron atom with an axial substituent. These molecules are particularly interesting for their optical properties offering potential applications for organic photovoltaics, organic light-emitting diodes, photodynamic therapy, and fluorescence imaging. In this review, we summarize how absorption and fluorescence properties can be finely tuned by substituent groups at either the periphery of the SubPc or at the axial position at the central boron atom. By suitable functionalization, fluorescence can for example be controlled by acid/base stimuli or by light/heat stimuli causing isomerization of an appended photo/thermoswitch. Moreover, optical properties can be tuned by contraction or expansion of the π-conjugated core. Key synthetic protocols for functionalization at peripheral and axial positions are also covered.",
author = "Mathias Dowds and Nielsen, {Mogens Br{\o}ndsted}",
year = "2021",
doi = "10.1039/d0me00150c",
language = "English",
volume = "6",
pages = "6--24",
journal = "Molecular Systems Design and Engineering",
issn = "2058-9689",
publisher = "Royal Society of Chemistry",

}

RIS

TY - JOUR

T1 - Controlling the optical properties of boron subphthalocyanines and their analogues

AU - Dowds, Mathias

AU - Nielsen, Mogens Brøndsted

PY - 2021

Y1 - 2021

N2 - Boron subphthalocyanines (SubPcs) are cone shaped π-conjugated molecules comprised of three azomethine-bridged isoindole units and a central boron atom with an axial substituent. These molecules are particularly interesting for their optical properties offering potential applications for organic photovoltaics, organic light-emitting diodes, photodynamic therapy, and fluorescence imaging. In this review, we summarize how absorption and fluorescence properties can be finely tuned by substituent groups at either the periphery of the SubPc or at the axial position at the central boron atom. By suitable functionalization, fluorescence can for example be controlled by acid/base stimuli or by light/heat stimuli causing isomerization of an appended photo/thermoswitch. Moreover, optical properties can be tuned by contraction or expansion of the π-conjugated core. Key synthetic protocols for functionalization at peripheral and axial positions are also covered.

AB - Boron subphthalocyanines (SubPcs) are cone shaped π-conjugated molecules comprised of three azomethine-bridged isoindole units and a central boron atom with an axial substituent. These molecules are particularly interesting for their optical properties offering potential applications for organic photovoltaics, organic light-emitting diodes, photodynamic therapy, and fluorescence imaging. In this review, we summarize how absorption and fluorescence properties can be finely tuned by substituent groups at either the periphery of the SubPc or at the axial position at the central boron atom. By suitable functionalization, fluorescence can for example be controlled by acid/base stimuli or by light/heat stimuli causing isomerization of an appended photo/thermoswitch. Moreover, optical properties can be tuned by contraction or expansion of the π-conjugated core. Key synthetic protocols for functionalization at peripheral and axial positions are also covered.

U2 - 10.1039/d0me00150c

DO - 10.1039/d0me00150c

M3 - Review

VL - 6

SP - 6

EP - 24

JO - Molecular Systems Design and Engineering

JF - Molecular Systems Design and Engineering

SN - 2058-9689

ER -

ID: 258766852