Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics

Publikation: Bidrag til bog/antologi/rapport › Bidrag til bog/antologi › Forskning

Standard

Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics. / Cacciarini, Martina; Nielsen, Mogens Brøndsted.

Molecular Photoswitches: Chemistry, Properties, and Applications . red. / Zbigniew L. Pianowski. Bind 1 Wiley-VCH, 2022. s. 379-400.

Publikation: Bidrag til bog/antologi/rapport › Bidrag til bog/antologi › Forskning

Harvard

Cacciarini, M & Nielsen, MB 2022, Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics. i ZL Pianowski (red.), Molecular Photoswitches: Chemistry, Properties, and Applications . bind 1, Wiley-VCH, s. 379-400. https://doi.org/10.1002/9783527827626.ch17

APA

Cacciarini, M., & Nielsen, M. B. (2022). Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics. I Z. L. Pianowski (red.), Molecular Photoswitches: Chemistry, Properties, and Applications (Bind 1, s. 379-400). Wiley-VCH. https://doi.org/10.1002/9783527827626.ch17

Vancouver

Cacciarini M, Nielsen MB. Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics. I Pianowski ZL, red., Molecular Photoswitches: Chemistry, Properties, and Applications . Bind 1. Wiley-VCH. 2022. s. 379-400 https://doi.org/10.1002/9783527827626.ch17

Author

Cacciarini, Martina ; Nielsen, Mogens Brøndsted. / Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics. Molecular Photoswitches: Chemistry, Properties, and Applications . red. / Zbigniew L. Pianowski. Bind 1 Wiley-VCH, 2022. s. 379-400

Bibtex

@inbook{05eca9aaabed4f9580b04a9b7dc2affe,
title = "Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics",
abstract = "This chapter focuses on the dihydroazulene/vinylheptafulvene (DHA/VHF) photo-/thermo-switch in the context of molecular electronics. It covers the general properties of this couple as well as synthetic protocols for synthesizing and functionalizing DHA. Functionalization methods rely in particular on the ready incorporation of a bromo substituent at the seven-membered ring of DHA and an iodophenyl at the five-membered ring, allowing for Pd-catalyzed cross-coupling reactions. Synthetically, the emphasis is on how to introduce sulfur end-groups for anchoring DHA molecules to metal electrodes. Single-molecule conductance studies reveal light-controlled conductance switching for several of these junctions. Of additional relevance for molecular electronics, various multimode switches for optical data storage are described.",
author = "Martina Cacciarini and Nielsen, {Mogens Br{\o}ndsted}",
year = "2022",
doi = "10.1002/9783527827626.ch17",
language = "English",
isbn = "9783527351046",
volume = "1",
pages = "379--400",
editor = "Pianowski, {Zbigniew L.}",
booktitle = "Molecular Photoswitches: Chemistry, Properties, and Applications",
publisher = "Wiley-VCH",
address = "Germany",

}

RIS

TY - CHAP

T1 - Dihydroazulene/Vinylheptafulvene (DHA/VHF) and Molecular Electronics

AU - Cacciarini, Martina

AU - Nielsen, Mogens Brøndsted

PY - 2022

Y1 - 2022

N2 - This chapter focuses on the dihydroazulene/vinylheptafulvene (DHA/VHF) photo-/thermo-switch in the context of molecular electronics. It covers the general properties of this couple as well as synthetic protocols for synthesizing and functionalizing DHA. Functionalization methods rely in particular on the ready incorporation of a bromo substituent at the seven-membered ring of DHA and an iodophenyl at the five-membered ring, allowing for Pd-catalyzed cross-coupling reactions. Synthetically, the emphasis is on how to introduce sulfur end-groups for anchoring DHA molecules to metal electrodes. Single-molecule conductance studies reveal light-controlled conductance switching for several of these junctions. Of additional relevance for molecular electronics, various multimode switches for optical data storage are described.

AB - This chapter focuses on the dihydroazulene/vinylheptafulvene (DHA/VHF) photo-/thermo-switch in the context of molecular electronics. It covers the general properties of this couple as well as synthetic protocols for synthesizing and functionalizing DHA. Functionalization methods rely in particular on the ready incorporation of a bromo substituent at the seven-membered ring of DHA and an iodophenyl at the five-membered ring, allowing for Pd-catalyzed cross-coupling reactions. Synthetically, the emphasis is on how to introduce sulfur end-groups for anchoring DHA molecules to metal electrodes. Single-molecule conductance studies reveal light-controlled conductance switching for several of these junctions. Of additional relevance for molecular electronics, various multimode switches for optical data storage are described.

U2 - 10.1002/9783527827626.ch17

DO - 10.1002/9783527827626.ch17

M3 - Book chapter

SN - 9783527351046

VL - 1

SP - 379

EP - 400

BT - Molecular Photoswitches: Chemistry, Properties, and Applications

A2 - Pianowski, Zbigniew L.

PB - Wiley-VCH

ER -

ID: 334719353