Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**

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Standard

Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**. / Grenier, Laura L. A.; Nielsen, Lea G.; Sørensen, Thomas J.

I: Analysis & Sensing, Bind 2, Nr. 6, 2022.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Grenier, LLA, Nielsen, LG & Sørensen, TJ 2022, 'Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**', Analysis & Sensing, bind 2, nr. 6. https://doi.org/10.1002/anse.202200033

APA

Grenier, L. L. A., Nielsen, L. G., & Sørensen, T. J. (2022). Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**. Analysis & Sensing, 2(6). https://doi.org/10.1002/anse.202200033

Vancouver

Grenier LLA, Nielsen LG, Sørensen TJ. Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**. Analysis & Sensing. 2022;2(6). https://doi.org/10.1002/anse.202200033

Author

Grenier, Laura L. A. ; Nielsen, Lea G. ; Sørensen, Thomas J. / Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**. I: Analysis & Sensing. 2022 ; Bind 2, Nr. 6.

Bibtex

@article{0be108c4a24e4875aa6c136c2fd0b537,
title = "Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**",
abstract = "Responsive lanthanide(III) complexes – europium(III) complexes in particular – have been the focus of studies for several decades. While responsive lanthanide complexes have been reported and investigated frequently, the supramolecular aspects and linear free-energy relationship have seen less attention. Here, we are revisiting five europium(III) complexes and investigating their binding to ten different guests, all with a primary interaction between the europium(III) ion and a bidentate carboxylate anion. The studies consisted of measuring emission spectra, analysing band behaviours of the europium transitions, and calculating lifetime isotherms. The media effect was also investigated, and by eliminating the impact of hydrophobic effects, we can show that selectivity in these host-guest systems can be tuned by the secondary lipophilic interactions.",
author = "Grenier, {Laura L. A.} and Nielsen, {Lea G.} and S{\o}rensen, {Thomas J.}",
year = "2022",
doi = "10.1002/anse.202200033",
language = "English",
volume = "2",
journal = "Analysis & Sensing",
issn = "2629-2742",
number = "6",

}

RIS

TY - JOUR

T1 - Effect of Lipophilicity in Oxyanion‐Responsive Europium(III) Complexes**

AU - Grenier, Laura L. A.

AU - Nielsen, Lea G.

AU - Sørensen, Thomas J.

PY - 2022

Y1 - 2022

N2 - Responsive lanthanide(III) complexes – europium(III) complexes in particular – have been the focus of studies for several decades. While responsive lanthanide complexes have been reported and investigated frequently, the supramolecular aspects and linear free-energy relationship have seen less attention. Here, we are revisiting five europium(III) complexes and investigating their binding to ten different guests, all with a primary interaction between the europium(III) ion and a bidentate carboxylate anion. The studies consisted of measuring emission spectra, analysing band behaviours of the europium transitions, and calculating lifetime isotherms. The media effect was also investigated, and by eliminating the impact of hydrophobic effects, we can show that selectivity in these host-guest systems can be tuned by the secondary lipophilic interactions.

AB - Responsive lanthanide(III) complexes – europium(III) complexes in particular – have been the focus of studies for several decades. While responsive lanthanide complexes have been reported and investigated frequently, the supramolecular aspects and linear free-energy relationship have seen less attention. Here, we are revisiting five europium(III) complexes and investigating their binding to ten different guests, all with a primary interaction between the europium(III) ion and a bidentate carboxylate anion. The studies consisted of measuring emission spectra, analysing band behaviours of the europium transitions, and calculating lifetime isotherms. The media effect was also investigated, and by eliminating the impact of hydrophobic effects, we can show that selectivity in these host-guest systems can be tuned by the secondary lipophilic interactions.

U2 - 10.1002/anse.202200033

DO - 10.1002/anse.202200033

M3 - Journal article

VL - 2

JO - Analysis & Sensing

JF - Analysis & Sensing

SN - 2629-2742

IS - 6

ER -

ID: 338981907