Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex

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Standard

Electrophilic Activation of Osmium-Nitrido Corroles : The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex. / Reinholdt, Anders; Alemayehu, Abraham B.; Gagnon, Kevin J.; Bendix, Jesper; Ghosh, Abhik.

I: Inorganic Chemistry, Bind 59, 2020, s. 5276-5280.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Reinholdt, A, Alemayehu, AB, Gagnon, KJ, Bendix, J & Ghosh, A 2020, 'Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex', Inorganic Chemistry, bind 59, s. 5276-5280. https://doi.org/10.1021/acs.inorgchem.0c00654

APA

Reinholdt, A., Alemayehu, A. B., Gagnon, K. J., Bendix, J., & Ghosh, A. (2020). Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex. Inorganic Chemistry, 59, 5276-5280. https://doi.org/10.1021/acs.inorgchem.0c00654

Vancouver

Reinholdt A, Alemayehu AB, Gagnon KJ, Bendix J, Ghosh A. Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex. Inorganic Chemistry. 2020;59:5276-5280. https://doi.org/10.1021/acs.inorgchem.0c00654

Author

Reinholdt, Anders ; Alemayehu, Abraham B. ; Gagnon, Kevin J. ; Bendix, Jesper ; Ghosh, Abhik. / Electrophilic Activation of Osmium-Nitrido Corroles : The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex. I: Inorganic Chemistry. 2020 ; Bind 59. s. 5276-5280.

Bibtex

@article{b7dddc7a8b6a4fb0afb3b4a76c6b6def,
title = "Electrophilic Activation of Osmium-Nitrido Corroles: The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex",
abstract = "Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouched. The OsN unit is also unaffected by a variety of other electrophilic and nucleophilic reagents. Upon photolysis, however, the anion of Zeise's salt associates with the nitrido ligand to generate an OsVIN - PtII complex. The very short OsN-Pt linkage [1.895(9)-1.917(8) {\AA}] and the downfield 195Pt NMR resonance (-2702 ppm) suggest that the OsN corrole acts as a π-accepting ligand toward the Pt(II) center. This finding represents a rare example of the successful photochemical activation of a metal-ligand multiple bond that is too kinetically inert to exhibit any appreciable reactivity under thermal conditions. {\textcopyright}",
author = "Anders Reinholdt and Alemayehu, {Abraham B.} and Gagnon, {Kevin J.} and Jesper Bendix and Abhik Ghosh",
year = "2020",
doi = "10.1021/acs.inorgchem.0c00654",
language = "English",
volume = "59",
pages = "5276--5280",
journal = "Inorganic Chemistry",
issn = "0020-1669",
publisher = "American Chemical Society",

}

RIS

TY - JOUR

T1 - Electrophilic Activation of Osmium-Nitrido Corroles

T2 - The OsN Triple Bond as a π-Acceptor Metallaligand in a Heterobimetallic OsVIN-PtII Complex

AU - Reinholdt, Anders

AU - Alemayehu, Abraham B.

AU - Gagnon, Kevin J.

AU - Bendix, Jesper

AU - Ghosh, Abhik

PY - 2020

Y1 - 2020

N2 - Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouched. The OsN unit is also unaffected by a variety of other electrophilic and nucleophilic reagents. Upon photolysis, however, the anion of Zeise's salt associates with the nitrido ligand to generate an OsVIN - PtII complex. The very short OsN-Pt linkage [1.895(9)-1.917(8) Å] and the downfield 195Pt NMR resonance (-2702 ppm) suggest that the OsN corrole acts as a π-accepting ligand toward the Pt(II) center. This finding represents a rare example of the successful photochemical activation of a metal-ligand multiple bond that is too kinetically inert to exhibit any appreciable reactivity under thermal conditions. ©

AB - Presented herein is a first investigation of the chemical reactivity of osmium-nitrido corroles, which are known for their unusual thermal, chemical, and photochemical stability. Elemental chlorine perchlorinates the β-positions of the triarylcorrole but leaves the OsN unit untouched. The OsN unit is also unaffected by a variety of other electrophilic and nucleophilic reagents. Upon photolysis, however, the anion of Zeise's salt associates with the nitrido ligand to generate an OsVIN - PtII complex. The very short OsN-Pt linkage [1.895(9)-1.917(8) Å] and the downfield 195Pt NMR resonance (-2702 ppm) suggest that the OsN corrole acts as a π-accepting ligand toward the Pt(II) center. This finding represents a rare example of the successful photochemical activation of a metal-ligand multiple bond that is too kinetically inert to exhibit any appreciable reactivity under thermal conditions. ©

U2 - 10.1021/acs.inorgchem.0c00654

DO - 10.1021/acs.inorgchem.0c00654

M3 - Journal article

C2 - 32227864

AN - SCOPUS:85082812300

VL - 59

SP - 5276

EP - 5280

JO - Inorganic Chemistry

JF - Inorganic Chemistry

SN - 0020-1669

ER -

ID: 240003041