Identification of OSSO as a near-UV absorber in the Venusian atmosphere
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Identification of OSSO as a near-UV absorber in the Venusian atmosphere. / Frandsen, Benjamin Normann; Wennberg, Paul O.; Kjærgaard, Henrik Grum.
I: Geophysical Research Letters, Bind 43, Nr. 21, 2016, s. 11,146-11,155.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Identification of OSSO as a near-UV absorber in the Venusian atmosphere
AU - Frandsen, Benjamin Normann
AU - Wennberg, Paul O.
AU - Kjærgaard, Henrik Grum
PY - 2016
Y1 - 2016
N2 - The planet Venus exhibits atmospheric absorption in the 320–400 nm wavelength range produced by unknown chemistry. We investigate electronic transitions in molecules that may exist in the atmosphere of Venus. We identify two different S2O2 isomers, cis-OSSO and trans-OSSO, which are formed in significant amounts and are removed predominantly by near-UV photolysis. We estimate the rate of photolysis of cis- and trans-OSSO in the Venusian atmosphere and find that they are good candidates to explain the enigmatic 320–400 nm near-UV absorption. Between 58 and 70 km, the calculated OSSO concentrations are similar to those of sulfur monoxide (SO), generally thought to be the second most abundant sulfur oxide on Venus.
AB - The planet Venus exhibits atmospheric absorption in the 320–400 nm wavelength range produced by unknown chemistry. We investigate electronic transitions in molecules that may exist in the atmosphere of Venus. We identify two different S2O2 isomers, cis-OSSO and trans-OSSO, which are formed in significant amounts and are removed predominantly by near-UV photolysis. We estimate the rate of photolysis of cis- and trans-OSSO in the Venusian atmosphere and find that they are good candidates to explain the enigmatic 320–400 nm near-UV absorption. Between 58 and 70 km, the calculated OSSO concentrations are similar to those of sulfur monoxide (SO), generally thought to be the second most abundant sulfur oxide on Venus.
KW - Near-UV absorption
KW - Sulfur oxides
KW - Venus Atmosphere
U2 - 10.1002/2016GL070916
DO - 10.1002/2016GL070916
M3 - Journal article
AN - SCOPUS:84998890674
VL - 43
SP - 11,146-11,155
JO - Geophysical Research Letters
JF - Geophysical Research Letters
SN - 0094-8276
IS - 21
ER -
ID: 170742141