Isomerization of metastable amine radical cations by dissociation-recombination
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Isomerization of metastable amine radical cations by dissociation-recombination. / Pedersen, Anders Holmen; Nielsen, Christian Benedikt; Bojesen, Gustav; Hammerum, Steen.
I: European Journal of Mass Spectrometry, Bind 21, Nr. 3, 2015, s. 635-639.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Isomerization of metastable amine radical cations by dissociation-recombination
AU - Pedersen, Anders Holmen
AU - Nielsen, Christian Benedikt
AU - Bojesen, Gustav
AU - Hammerum, Steen
PY - 2015
Y1 - 2015
N2 - The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier to account for the conspicuous absence of the conventional a-cleavage among the major fragmentation reactions of the metastable molecular ions of primary amines.
AB - The metastable molecular ions of primary aliphatic amines branched at C2 can isomerize by cleavage-recombination, thereby facilitating fragmentation reactions that require less energy than simple cleavage of the initial molecular ion. This process complements the reactions described by Audier to account for the conspicuous absence of the conventional a-cleavage among the major fragmentation reactions of the metastable molecular ions of primary amines.
U2 - 10.1255/ejms.1342
DO - 10.1255/ejms.1342
M3 - Journal article
C2 - 26307742
VL - 21
SP - 635
EP - 639
JO - European Journal of Mass Spectrometry
JF - European Journal of Mass Spectrometry
SN - 1469-0667
IS - 3
ER -
ID: 144040127