Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene

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Standard

Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene. / Frøsig, L.; Nielsen, O. J.; Bilde, M.; Wallington, T. J.; Orlando, J. J.; Tyndall, G. S.

I: Journal of Physical Chemistry A, Bind 104, Nr. 48, 07.12.2000, s. 11328-11331.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Frøsig, L, Nielsen, OJ, Bilde, M, Wallington, TJ, Orlando, JJ & Tyndall, GS 2000, 'Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene', Journal of Physical Chemistry A, bind 104, nr. 48, s. 11328-11331. https://doi.org/10.1021/jp002696o

APA

Frøsig, L., Nielsen, O. J., Bilde, M., Wallington, T. J., Orlando, J. J., & Tyndall, G. S. (2000). Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene. Journal of Physical Chemistry A, 104(48), 11328-11331. https://doi.org/10.1021/jp002696o

Vancouver

Frøsig L, Nielsen OJ, Bilde M, Wallington TJ, Orlando JJ, Tyndall GS. Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene. Journal of Physical Chemistry A. 2000 dec. 7;104(48):11328-11331. https://doi.org/10.1021/jp002696o

Author

Frøsig, L. ; Nielsen, O. J. ; Bilde, M. ; Wallington, T. J. ; Orlando, J. J. ; Tyndall, G. S. / Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene. I: Journal of Physical Chemistry A. 2000 ; Bind 104, Nr. 48. s. 11328-11331.

Bibtex

@article{eb2dcf8f61fb4ef0865e3a1fecf1e4a0,
title = "Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene",
abstract = "Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with nitrobenzene (C6H5NO2) in 10-700 Torr of N2, or air, at 296 K. The reaction proceeds with a rate constant k(Cl + C6H5NO2) = (9.3 ± 1.9) × 10-13 cm3 molecule-1 s-1 to give C6H5Cl and NO2 products in essentially 100% yield. The observed product yields suggest that the reaction proceeds via a displacement mechanism (probably addition followed by elimination). The UV-visible absorption spectrum of C6H5NO2 was measured. Photolysis of C6H5NO2 is estimated to occur at a rate of (3 ± 2) × 10-5 s-1 for a solar zenith angle of 25° (representative of a typical summer day at 40°N) and is likely to be the dominant atmospheric loss mechanism for C6H5NO2.",
author = "L. Fr{\o}sig and Nielsen, {O. J.} and M. Bilde and Wallington, {T. J.} and Orlando, {J. J.} and Tyndall, {G. S.}",
year = "2000",
month = dec,
day = "7",
doi = "10.1021/jp002696o",
language = "English",
volume = "104",
pages = "11328--11331",
journal = "Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory",
issn = "1089-5639",
publisher = "American Chemical Society",
number = "48",

}

RIS

TY - JOUR

T1 - Kinetics and mechanism of the reaction of Cl atoms with nitrobenzene

AU - Frøsig, L.

AU - Nielsen, O. J.

AU - Bilde, M.

AU - Wallington, T. J.

AU - Orlando, J. J.

AU - Tyndall, G. S.

PY - 2000/12/7

Y1 - 2000/12/7

N2 - Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with nitrobenzene (C6H5NO2) in 10-700 Torr of N2, or air, at 296 K. The reaction proceeds with a rate constant k(Cl + C6H5NO2) = (9.3 ± 1.9) × 10-13 cm3 molecule-1 s-1 to give C6H5Cl and NO2 products in essentially 100% yield. The observed product yields suggest that the reaction proceeds via a displacement mechanism (probably addition followed by elimination). The UV-visible absorption spectrum of C6H5NO2 was measured. Photolysis of C6H5NO2 is estimated to occur at a rate of (3 ± 2) × 10-5 s-1 for a solar zenith angle of 25° (representative of a typical summer day at 40°N) and is likely to be the dominant atmospheric loss mechanism for C6H5NO2.

AB - Smog chamber/FTIR techniques were used to study the kinetics and mechanism of the reaction of Cl atoms with nitrobenzene (C6H5NO2) in 10-700 Torr of N2, or air, at 296 K. The reaction proceeds with a rate constant k(Cl + C6H5NO2) = (9.3 ± 1.9) × 10-13 cm3 molecule-1 s-1 to give C6H5Cl and NO2 products in essentially 100% yield. The observed product yields suggest that the reaction proceeds via a displacement mechanism (probably addition followed by elimination). The UV-visible absorption spectrum of C6H5NO2 was measured. Photolysis of C6H5NO2 is estimated to occur at a rate of (3 ± 2) × 10-5 s-1 for a solar zenith angle of 25° (representative of a typical summer day at 40°N) and is likely to be the dominant atmospheric loss mechanism for C6H5NO2.

UR - http://www.scopus.com/inward/record.url?scp=0034514071&partnerID=8YFLogxK

U2 - 10.1021/jp002696o

DO - 10.1021/jp002696o

M3 - Journal article

AN - SCOPUS:0034514071

VL - 104

SP - 11328

EP - 11331

JO - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

JF - Journal of Physical Chemistry Part A: Molecules, Spectroscopy, Kinetics, Environment and General Theory

SN - 1089-5639

IS - 48

ER -

ID: 223681038