Kinetics of the reaction of CH3O2 radicals with NO2

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Kinetics of the reaction of CH3O2 radicals with NO2. / Wallington, T. J.; Nielsen, O. J.

I: Chemical Physics Letters, Bind 313, Nr. 3-4, 12.11.1999, s. 456-460.

Publikation: Bidrag til tidsskriftTidsskriftartikelForskningfagfællebedømt

Harvard

Wallington, TJ & Nielsen, OJ 1999, 'Kinetics of the reaction of CH3O2 radicals with NO2', Chemical Physics Letters, bind 313, nr. 3-4, s. 456-460. https://doi.org/10.1016/S0009-2614(99)01072-6

APA

Wallington, T. J., & Nielsen, O. J. (1999). Kinetics of the reaction of CH3O2 radicals with NO2. Chemical Physics Letters, 313(3-4), 456-460. https://doi.org/10.1016/S0009-2614(99)01072-6

Vancouver

Wallington TJ, Nielsen OJ. Kinetics of the reaction of CH3O2 radicals with NO2. Chemical Physics Letters. 1999 nov. 12;313(3-4):456-460. https://doi.org/10.1016/S0009-2614(99)01072-6

Author

Wallington, T. J. ; Nielsen, O. J. / Kinetics of the reaction of CH3O2 radicals with NO2. I: Chemical Physics Letters. 1999 ; Bind 313, Nr. 3-4. s. 456-460.

Bibtex

@article{5d2668f101e34dd9bf14ada1caff0519,
title = "Kinetics of the reaction of CH3O2 radicals with NO2",
abstract = "The kinetics of the gas-phase reaction of CH3O2 radicals with NO2 were studied at 295 K in 0.5-14 atm of SF6 diluent using pulse radiolysis combined with time-resolved UV-VIS spectroscopy. Rate data were obtained by following the loss of CH3O2 using a monitoring wavelength of 260 nm. The results were well described using the Troe formula with Fc=0.40±0.09, k0=(1.46±0.50)×10-30 cm6 molecule-1 s-1 and k∞=(1.81±0.25)×10-11 cm3 molecule-1 s-1. These results are compared to the previous data and discussed in terms of reactivity trends and the atmospheric chemistry of peroxy radicals.",
author = "Wallington, {T. J.} and Nielsen, {O. J.}",
year = "1999",
month = nov,
day = "12",
doi = "10.1016/S0009-2614(99)01072-6",
language = "English",
volume = "313",
pages = "456--460",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "3-4",

}

RIS

TY - JOUR

T1 - Kinetics of the reaction of CH3O2 radicals with NO2

AU - Wallington, T. J.

AU - Nielsen, O. J.

PY - 1999/11/12

Y1 - 1999/11/12

N2 - The kinetics of the gas-phase reaction of CH3O2 radicals with NO2 were studied at 295 K in 0.5-14 atm of SF6 diluent using pulse radiolysis combined with time-resolved UV-VIS spectroscopy. Rate data were obtained by following the loss of CH3O2 using a monitoring wavelength of 260 nm. The results were well described using the Troe formula with Fc=0.40±0.09, k0=(1.46±0.50)×10-30 cm6 molecule-1 s-1 and k∞=(1.81±0.25)×10-11 cm3 molecule-1 s-1. These results are compared to the previous data and discussed in terms of reactivity trends and the atmospheric chemistry of peroxy radicals.

AB - The kinetics of the gas-phase reaction of CH3O2 radicals with NO2 were studied at 295 K in 0.5-14 atm of SF6 diluent using pulse radiolysis combined with time-resolved UV-VIS spectroscopy. Rate data were obtained by following the loss of CH3O2 using a monitoring wavelength of 260 nm. The results were well described using the Troe formula with Fc=0.40±0.09, k0=(1.46±0.50)×10-30 cm6 molecule-1 s-1 and k∞=(1.81±0.25)×10-11 cm3 molecule-1 s-1. These results are compared to the previous data and discussed in terms of reactivity trends and the atmospheric chemistry of peroxy radicals.

UR - http://www.scopus.com/inward/record.url?scp=0004470220&partnerID=8YFLogxK

U2 - 10.1016/S0009-2614(99)01072-6

DO - 10.1016/S0009-2614(99)01072-6

M3 - Journal article

AN - SCOPUS:0004470220

VL - 313

SP - 456

EP - 460

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 3-4

ER -

ID: 223681227