Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction

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Standard

Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction. / Nikitin, Sergei; Lie, Yann; Diness, Frederik.

I: Macromolecular Chemistry and Physics, Bind 223, Nr. 13, 2022, s. 2100484.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Nikitin, S, Lie, Y & Diness, F 2022, 'Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction', Macromolecular Chemistry and Physics, bind 223, nr. 13, s. 2100484. https://doi.org/10.1002/macp.202100484

APA

Nikitin, S., Lie, Y., & Diness, F. (2022). Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction. Macromolecular Chemistry and Physics, 223(13), 2100484. https://doi.org/10.1002/macp.202100484

Vancouver

Nikitin S, Lie Y, Diness F. Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction. Macromolecular Chemistry and Physics. 2022;223(13):2100484. https://doi.org/10.1002/macp.202100484

Author

Nikitin, Sergei ; Lie, Yann ; Diness, Frederik. / Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction. I: Macromolecular Chemistry and Physics. 2022 ; Bind 223, Nr. 13. s. 2100484.

Bibtex

@article{d28ce40b23ff4838a95e3fbbdcc7e561,
title = "Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction",
abstract = "A new type of lignin-inspired polybenzylethersulfone (PBES) is synthesized by SNAr reaction in 75% yield. Success of the polymerization is confirmed by ATR-IR, 1H, 13C NMR spectroscopy and MALDI-TOF MS. The obtained polysulfone is solvent casted into a film which displays high thermal and chemical stability. Treatment with 33% HBr in acetic acid leads to degradation of the material. The isolated degradation products are identified and repolymerized back into PBES demonstrating the opportunity for chemical recycling of this new polymer.",
keywords = "degradable polymers, high temperatures polymers, lignin, polysulfones, SAr Reaction",
author = "Sergei Nikitin and Yann Lie and Frederik Diness",
note = "Funding Information: The authors are grateful for the financial support from the Villum Foundation (project #36126). The authors also acknowledge the general support from the University of Copenhagen. Publisher Copyright: {\textcopyright} 2022 The Authors. Macromolecular Chemistry and Physics published by Wiley-VCH GmbH.",
year = "2022",
doi = "10.1002/macp.202100484",
language = "English",
volume = "223",
pages = "2100484",
journal = "Macromolecular Chemistry and Physics",
issn = "1022-1352",
publisher = "Wiley - V C H Verlag GmbH & Co. KGaA",
number = "13",

}

RIS

TY - JOUR

T1 - Lignin-Inspired Polybenzylethersulfone Synthesis via SNAr Reaction

AU - Nikitin, Sergei

AU - Lie, Yann

AU - Diness, Frederik

N1 - Funding Information: The authors are grateful for the financial support from the Villum Foundation (project #36126). The authors also acknowledge the general support from the University of Copenhagen. Publisher Copyright: © 2022 The Authors. Macromolecular Chemistry and Physics published by Wiley-VCH GmbH.

PY - 2022

Y1 - 2022

N2 - A new type of lignin-inspired polybenzylethersulfone (PBES) is synthesized by SNAr reaction in 75% yield. Success of the polymerization is confirmed by ATR-IR, 1H, 13C NMR spectroscopy and MALDI-TOF MS. The obtained polysulfone is solvent casted into a film which displays high thermal and chemical stability. Treatment with 33% HBr in acetic acid leads to degradation of the material. The isolated degradation products are identified and repolymerized back into PBES demonstrating the opportunity for chemical recycling of this new polymer.

AB - A new type of lignin-inspired polybenzylethersulfone (PBES) is synthesized by SNAr reaction in 75% yield. Success of the polymerization is confirmed by ATR-IR, 1H, 13C NMR spectroscopy and MALDI-TOF MS. The obtained polysulfone is solvent casted into a film which displays high thermal and chemical stability. Treatment with 33% HBr in acetic acid leads to degradation of the material. The isolated degradation products are identified and repolymerized back into PBES demonstrating the opportunity for chemical recycling of this new polymer.

KW - degradable polymers

KW - high temperatures polymers

KW - lignin

KW - polysulfones

KW - SAr Reaction

U2 - 10.1002/macp.202100484

DO - 10.1002/macp.202100484

M3 - Journal article

AN - SCOPUS:85128868654

VL - 223

SP - 2100484

JO - Macromolecular Chemistry and Physics

JF - Macromolecular Chemistry and Physics

SN - 1022-1352

IS - 13

ER -

ID: 306152941