TY - CHAP

T1 - Molecular Fluoride-Bridged 3d-4f Complexes and Their Magnetic Properties

AU - Pedersen, K. S.

AU - Bendix, J.

PY - 2016

Y1 - 2016

N2 - Fluoride-bridged systems benefit from the redox- and spectroscopic innocence of fluoride, which facilitates spectroscopic characterization and elucidation of their electronic structures. Although fluorine is often thought of as the "nonstick" element par excellence, fluoride-bridging can be utilized efficiently in tailored synthesis of polynuclear complexes and extended structures. In particular, the strong affinity of the lanthanides for fluoride makes it a good choice for directed synthesis of mixed lanthanide-transition metal complexes. Despite the competition from formation of lanthanide trifluorides with very high lattice enthalpies, building block approaches are not limited to robust systems and use of labile transition metal fluoride complexes has met with unexpected success. The physical properties of fluoride-bridged 3d-4f systems are crucially dependent on coordination geometries, which can be controlled to a fair extent via the geometric preferences of fluoride as the bridging entity.

AB - Fluoride-bridged systems benefit from the redox- and spectroscopic innocence of fluoride, which facilitates spectroscopic characterization and elucidation of their electronic structures. Although fluorine is often thought of as the "nonstick" element par excellence, fluoride-bridging can be utilized efficiently in tailored synthesis of polynuclear complexes and extended structures. In particular, the strong affinity of the lanthanides for fluoride makes it a good choice for directed synthesis of mixed lanthanide-transition metal complexes. Despite the competition from formation of lanthanide trifluorides with very high lattice enthalpies, building block approaches are not limited to robust systems and use of labile transition metal fluoride complexes has met with unexpected success. The physical properties of fluoride-bridged 3d-4f systems are crucially dependent on coordination geometries, which can be controlled to a fair extent via the geometric preferences of fluoride as the bridging entity.

KW - Fluoride bridging

KW - Lanthanide

KW - Magnetism

KW - Magnetocaloric effect

KW - XMCD

U2 - 10.1016/B978-0-12-801639-8.00011-8

DO - 10.1016/B978-0-12-801639-8.00011-8

M3 - Book chapter

AN - SCOPUS:84969638287

SN - 9780128016398

T3 - Progress in Fluorine Science Series

SP - 213

EP - 230

BT - Photonic and Electronic Properties of Fluoride Materials

PB - Elsevier

ER -