Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation

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Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation. / Deshmukh, Prathmesh; Satapathy, Sitakanta; Michail, Evripidis; Olsson, Andrew H.; Bushati, Rezlind; Yadav, Ravindra Kumar; Khatoniar, Mandeep; Chen, Junsheng; John, George; Laursen, Bo W.; Flood, Amar H.; Sfeir, Matthew Y.; Menon, Vinod M.

I: ACS Photonics, Bind 11, Nr. 2, 2024, s. 348−355.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Deshmukh, P, Satapathy, S, Michail, E, Olsson, AH, Bushati, R, Yadav, RK, Khatoniar, M, Chen, J, John, G, Laursen, BW, Flood, AH, Sfeir, MY & Menon, VM 2024, 'Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation', ACS Photonics, bind 11, nr. 2, s. 348−355. https://doi.org/10.1021/acsphotonics.3c01547

APA

Deshmukh, P., Satapathy, S., Michail, E., Olsson, A. H., Bushati, R., Yadav, R. K., Khatoniar, M., Chen, J., John, G., Laursen, B. W., Flood, A. H., Sfeir, M. Y., & Menon, V. M. (2024). Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation. ACS Photonics, 11(2), 348−355. https://doi.org/10.1021/acsphotonics.3c01547

Vancouver

Deshmukh P, Satapathy S, Michail E, Olsson AH, Bushati R, Yadav RK o.a. Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation. ACS Photonics. 2024;11(2):348−355. https://doi.org/10.1021/acsphotonics.3c01547

Author

Deshmukh, Prathmesh ; Satapathy, Sitakanta ; Michail, Evripidis ; Olsson, Andrew H. ; Bushati, Rezlind ; Yadav, Ravindra Kumar ; Khatoniar, Mandeep ; Chen, Junsheng ; John, George ; Laursen, Bo W. ; Flood, Amar H. ; Sfeir, Matthew Y. ; Menon, Vinod M. / Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation. I: ACS Photonics. 2024 ; Bind 11, Nr. 2. s. 348−355.

Bibtex

@article{189b45778ec845c6b9cb3662686999b4,
title = "Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation",
abstract = "Exciton-polaritons (EP), half-light half-matter quasiparticles that form in optical cavities, are attractive platforms for creating macroscopic coherent states such as Bose-Einstein condensation (BEC). EPs based on organic molecules are of particular interest for realizing such states at room temperature while offering the promise of synthetic tunability. However, the demonstrations of such condensates have been limited to a few specific molecular systems (Keeling et al. Bose-Einstein condensation of exciton-polaritons in organic microcavities. Annual Review of Physical Chemistry 2020, 71, 435-459). Here we report a universal platform for realizing molecular polariton condensates using commercial dyes that solve long-standing material challenges. This solution is made possible using a new and programmable molecular material called small-molecule, ionic isolation lattices (SMILES) with the potential to incorporate a wide array of molecular fluorophores (Benson et al. Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles. Chem 2020, 6, 1978-1997). We show EP condensation in rhodamine by incorporating it into a SMILES lattice placed in a planar microcavity. The SMILES approach overcomes the major drawbacks of organic molecular photophysical systems, such as self-quenching, which sets the foundation for realizing practical polaritonic devices operating at ambient temperatures covering a wide spectral range.",
keywords = "Bose−Einstein condensation, exciton-polaritons, molecular engineering, organic dyes, polariton lasing, programmable materials",
author = "Prathmesh Deshmukh and Sitakanta Satapathy and Evripidis Michail and Olsson, {Andrew H.} and Rezlind Bushati and Yadav, {Ravindra Kumar} and Mandeep Khatoniar and Junsheng Chen and George John and Laursen, {Bo W.} and Flood, {Amar H.} and Sfeir, {Matthew Y.} and Menon, {Vinod M.}",
note = "Funding Information: V.M.M., S.S., and R.K.Y. were supported by the U.S. Air Force Office of Scientific Research − MURI Grant FA9550-22-1-0317. S.S., P.D., and R.B. acknowledge support from the US National Science Foundation (NSF− QTAQS program OMA−1936351. M.Y.S. work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award No. DE-SC0022036. A.H.O. and A.H.F. acknowledge support from the U.S. National Science Foundation (DMR-2118423). Publisher Copyright: {\textcopyright} 2024 American Chemical Society",
year = "2024",
doi = "10.1021/acsphotonics.3c01547",
language = "English",
volume = "11",
pages = "348−355",
journal = "ACS Photonics",
issn = "2330-4022",
publisher = "American Chemical Society",
number = "2",

}

RIS

TY - JOUR

T1 - Plug-and-Play Molecular Approach for Room Temperature Polariton Condensation

AU - Deshmukh, Prathmesh

AU - Satapathy, Sitakanta

AU - Michail, Evripidis

AU - Olsson, Andrew H.

AU - Bushati, Rezlind

AU - Yadav, Ravindra Kumar

AU - Khatoniar, Mandeep

AU - Chen, Junsheng

AU - John, George

AU - Laursen, Bo W.

AU - Flood, Amar H.

AU - Sfeir, Matthew Y.

AU - Menon, Vinod M.

N1 - Funding Information: V.M.M., S.S., and R.K.Y. were supported by the U.S. Air Force Office of Scientific Research − MURI Grant FA9550-22-1-0317. S.S., P.D., and R.B. acknowledge support from the US National Science Foundation (NSF− QTAQS program OMA−1936351. M.Y.S. work was supported by the U.S. Department of Energy, Office of Science, Office of Basic Energy Sciences under Award No. DE-SC0022036. A.H.O. and A.H.F. acknowledge support from the U.S. National Science Foundation (DMR-2118423). Publisher Copyright: © 2024 American Chemical Society

PY - 2024

Y1 - 2024

N2 - Exciton-polaritons (EP), half-light half-matter quasiparticles that form in optical cavities, are attractive platforms for creating macroscopic coherent states such as Bose-Einstein condensation (BEC). EPs based on organic molecules are of particular interest for realizing such states at room temperature while offering the promise of synthetic tunability. However, the demonstrations of such condensates have been limited to a few specific molecular systems (Keeling et al. Bose-Einstein condensation of exciton-polaritons in organic microcavities. Annual Review of Physical Chemistry 2020, 71, 435-459). Here we report a universal platform for realizing molecular polariton condensates using commercial dyes that solve long-standing material challenges. This solution is made possible using a new and programmable molecular material called small-molecule, ionic isolation lattices (SMILES) with the potential to incorporate a wide array of molecular fluorophores (Benson et al. Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles. Chem 2020, 6, 1978-1997). We show EP condensation in rhodamine by incorporating it into a SMILES lattice placed in a planar microcavity. The SMILES approach overcomes the major drawbacks of organic molecular photophysical systems, such as self-quenching, which sets the foundation for realizing practical polaritonic devices operating at ambient temperatures covering a wide spectral range.

AB - Exciton-polaritons (EP), half-light half-matter quasiparticles that form in optical cavities, are attractive platforms for creating macroscopic coherent states such as Bose-Einstein condensation (BEC). EPs based on organic molecules are of particular interest for realizing such states at room temperature while offering the promise of synthetic tunability. However, the demonstrations of such condensates have been limited to a few specific molecular systems (Keeling et al. Bose-Einstein condensation of exciton-polaritons in organic microcavities. Annual Review of Physical Chemistry 2020, 71, 435-459). Here we report a universal platform for realizing molecular polariton condensates using commercial dyes that solve long-standing material challenges. This solution is made possible using a new and programmable molecular material called small-molecule, ionic isolation lattices (SMILES) with the potential to incorporate a wide array of molecular fluorophores (Benson et al. Plug-and-Play Optical Materials from Fluorescent Dyes and Macrocycles. Chem 2020, 6, 1978-1997). We show EP condensation in rhodamine by incorporating it into a SMILES lattice placed in a planar microcavity. The SMILES approach overcomes the major drawbacks of organic molecular photophysical systems, such as self-quenching, which sets the foundation for realizing practical polaritonic devices operating at ambient temperatures covering a wide spectral range.

KW - Bose−Einstein condensation

KW - exciton-polaritons

KW - molecular engineering

KW - organic dyes

KW - polariton lasing

KW - programmable materials

U2 - 10.1021/acsphotonics.3c01547

DO - 10.1021/acsphotonics.3c01547

M3 - Journal article

AN - SCOPUS:85184743268

VL - 11

SP - 348−355

JO - ACS Photonics

JF - ACS Photonics

SN - 2330-4022

IS - 2

ER -

ID: 383391782