Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Standard

Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase. / Langer, Sarka; Ljungström, Evert; Ellermann, Thomas; Nielsen, Ole J.; Sehested, Jens.

I: Chemical Physics Letters, Bind 240, Nr. 5-6, 07.07.1995, s. 499-505.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Langer, S, Ljungström, E, Ellermann, T, Nielsen, OJ & Sehested, J 1995, 'Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase', Chemical Physics Letters, bind 240, nr. 5-6, s. 499-505. https://doi.org/10.1016/0009-2614(95)00571-K

APA

Langer, S., Ljungström, E., Ellermann, T., Nielsen, O. J., & Sehested, J. (1995). Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase. Chemical Physics Letters, 240(5-6), 499-505. https://doi.org/10.1016/0009-2614(95)00571-K

Vancouver

Langer S, Ljungström E, Ellermann T, Nielsen OJ, Sehested J. Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase. Chemical Physics Letters. 1995 jul. 7;240(5-6):499-505. https://doi.org/10.1016/0009-2614(95)00571-K

Author

Langer, Sarka ; Ljungström, Evert ; Ellermann, Thomas ; Nielsen, Ole J. ; Sehested, Jens. / Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase. I: Chemical Physics Letters. 1995 ; Bind 240, Nr. 5-6. s. 499-505.

Bibtex

@article{3877865929874caa872a76d14d102fa3,
title = "Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase",
abstract = "UV spectra and kinetics for the reactions of alkyl and alkylperoxy radicals from methyl tert-butyl ether (MTBE) were studied in 1 atm of SF6 by the pulse radiolysis-UV absorption technique. UV spectra for the radical mixtures were quantified from 215 to 340 nm. At 240 nm. σR = (2.6 ± 0.4) × 10-18 cm2 molecule-1 and σRO2 = (4.1 ± 0.6) × 10-18 cm2 molecule-1 (base e). The rate constant for the self-reaction of the alkyl radicals is (2.5 ± 1.1) × 10-11 cm3 molecule-1 s-1. The rate constants for reaction of the alkyl radicals with molecular oxygen and the alkylperoxy radicals with NO and NO2 are (9.1 ± 1.5) × 10-13, (4.3 ± 1.6) × 10-12 and (1.2 ± 0.3) × 10-11 cm3 molecule-1 s-1, respectively. The rate constants given above refer to reaction at the tert-butyl side of the molecule.",
author = "Sarka Langer and Evert Ljungstr{\"o}m and Thomas Ellermann and Nielsen, {Ole J.} and Jens Sehested",
year = "1995",
month = jul,
day = "7",
doi = "10.1016/0009-2614(95)00571-K",
language = "English",
volume = "240",
pages = "499--505",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "5-6",

}

RIS

TY - JOUR

T1 - Pulse radiolysis study of reactions of alkyl and alkylperoxy radicals originating from methyl tert-butyl ether in the gas phase

AU - Langer, Sarka

AU - Ljungström, Evert

AU - Ellermann, Thomas

AU - Nielsen, Ole J.

AU - Sehested, Jens

PY - 1995/7/7

Y1 - 1995/7/7

N2 - UV spectra and kinetics for the reactions of alkyl and alkylperoxy radicals from methyl tert-butyl ether (MTBE) were studied in 1 atm of SF6 by the pulse radiolysis-UV absorption technique. UV spectra for the radical mixtures were quantified from 215 to 340 nm. At 240 nm. σR = (2.6 ± 0.4) × 10-18 cm2 molecule-1 and σRO2 = (4.1 ± 0.6) × 10-18 cm2 molecule-1 (base e). The rate constant for the self-reaction of the alkyl radicals is (2.5 ± 1.1) × 10-11 cm3 molecule-1 s-1. The rate constants for reaction of the alkyl radicals with molecular oxygen and the alkylperoxy radicals with NO and NO2 are (9.1 ± 1.5) × 10-13, (4.3 ± 1.6) × 10-12 and (1.2 ± 0.3) × 10-11 cm3 molecule-1 s-1, respectively. The rate constants given above refer to reaction at the tert-butyl side of the molecule.

AB - UV spectra and kinetics for the reactions of alkyl and alkylperoxy radicals from methyl tert-butyl ether (MTBE) were studied in 1 atm of SF6 by the pulse radiolysis-UV absorption technique. UV spectra for the radical mixtures were quantified from 215 to 340 nm. At 240 nm. σR = (2.6 ± 0.4) × 10-18 cm2 molecule-1 and σRO2 = (4.1 ± 0.6) × 10-18 cm2 molecule-1 (base e). The rate constant for the self-reaction of the alkyl radicals is (2.5 ± 1.1) × 10-11 cm3 molecule-1 s-1. The rate constants for reaction of the alkyl radicals with molecular oxygen and the alkylperoxy radicals with NO and NO2 are (9.1 ± 1.5) × 10-13, (4.3 ± 1.6) × 10-12 and (1.2 ± 0.3) × 10-11 cm3 molecule-1 s-1, respectively. The rate constants given above refer to reaction at the tert-butyl side of the molecule.

UR - http://www.scopus.com/inward/record.url?scp=0010478821&partnerID=8YFLogxK

U2 - 10.1016/0009-2614(95)00571-K

DO - 10.1016/0009-2614(95)00571-K

M3 - Journal article

AN - SCOPUS:0010478821

VL - 240

SP - 499

EP - 505

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 5-6

ER -

ID: 228191863