Rate coefficients for reactions of OH radicals with CH3 D, CH2 D2 , CHD3 , and CD4
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Rate coefficients for reactions of OH radicals with CH3 D, CH2 D2 , CHD3 , and CD4. / Frederickson, Louise Bøge; Andersen, Simone Thirstrup; Nielsen, Ole John.
I: International Journal of Chemical Kinetics, Bind 51, Nr. 6, 2019, s. 390-394.Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt
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TY - JOUR
T1 - Rate coefficients for reactions of OH radicals with CH3 D, CH2 D2 , CHD3 , and CD4
AU - Frederickson, Louise Bøge
AU - Andersen, Simone Thirstrup
AU - Nielsen, Ole John
PY - 2019
Y1 - 2019
N2 - Fourier transform infrared (FTIR) smog chamber techniques were used to investigate the atmospheric chemistry of the isotopologues of methane. Relative rate measurements were performed to determine the kinetics of the reaction of the isotopologues of methane with OH radicals in cm 3 molecule −1 s −1 units: k(CH 3 D + OH) = (5.19 ± 0.90) × 10 −15 , k(CH 2 D 2 + OH) = (4.11 ± 0.74) × 10 −15 , k(CHD 3 + OH) = (2.14 ± 0.43) × 10 −15 , and k(CD 4 + OH) = (1.17 ± 0.19) × 10 −15 in 700 Torr of air diluent at 296 ± 2 K. Using the determined OH rate coefficients, the atmospheric lifetimes for CH 4– x D x (x = 1–4) were estimated to be 6.1, 7.7, 14.8, and 27.0 years, respectively. The results are discussed in relation to previous measurements of these rate coefficients.
AB - Fourier transform infrared (FTIR) smog chamber techniques were used to investigate the atmospheric chemistry of the isotopologues of methane. Relative rate measurements were performed to determine the kinetics of the reaction of the isotopologues of methane with OH radicals in cm 3 molecule −1 s −1 units: k(CH 3 D + OH) = (5.19 ± 0.90) × 10 −15 , k(CH 2 D 2 + OH) = (4.11 ± 0.74) × 10 −15 , k(CHD 3 + OH) = (2.14 ± 0.43) × 10 −15 , and k(CD 4 + OH) = (1.17 ± 0.19) × 10 −15 in 700 Torr of air diluent at 296 ± 2 K. Using the determined OH rate coefficients, the atmospheric lifetimes for CH 4– x D x (x = 1–4) were estimated to be 6.1, 7.7, 14.8, and 27.0 years, respectively. The results are discussed in relation to previous measurements of these rate coefficients.
KW - deuterated methanes
KW - isotope effects
KW - isotopologues
KW - OH kinetics
U2 - 10.1002/kin.21262
DO - 10.1002/kin.21262
M3 - Journal article
AN - SCOPUS:85062369115
VL - 51
SP - 390
EP - 394
JO - International Journal of Chemical Kinetics
JF - International Journal of Chemical Kinetics
SN - 0538-8066
IS - 6
ER -
ID: 216915202