Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K

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Standard

Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K. / Nielsen, Ole J.; Sidebottom, Howard W.; Donlon, Michael; Treacy, Jack.

I: International Journal of Chemical Kinetics, Bind 23, Nr. 12, 01.01.1991, s. 1095-1109.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Nielsen, OJ, Sidebottom, HW, Donlon, M & Treacy, J 1991, 'Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K', International Journal of Chemical Kinetics, bind 23, nr. 12, s. 1095-1109. https://doi.org/10.1002/kin.550231204

APA

Nielsen, O. J., Sidebottom, H. W., Donlon, M., & Treacy, J. (1991). Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K. International Journal of Chemical Kinetics, 23(12), 1095-1109. https://doi.org/10.1002/kin.550231204

Vancouver

Nielsen OJ, Sidebottom HW, Donlon M, Treacy J. Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K. International Journal of Chemical Kinetics. 1991 jan. 1;23(12):1095-1109. https://doi.org/10.1002/kin.550231204

Author

Nielsen, Ole J. ; Sidebottom, Howard W. ; Donlon, Michael ; Treacy, Jack. / Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K. I: International Journal of Chemical Kinetics. 1991 ; Bind 23, Nr. 12. s. 1095-1109.

Bibtex

@article{f4f9f293fb2d463db8345084b95b2216,
title = "Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K",
abstract = "Rate constants for the reactions of OH radicals and Cl atoms with CH3ONO, C2H5ONO, n‐C3H7ONO, n‐C4H9ONO, and n‐C5H11ONO have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a relative rate method involving simultaneous measurement of the loss of the nitrite and the reference compound. The Cl rate constants were measured using the relative rate method. Values of the rate constants in units of 10−13 cm3 molecule−1 s−1 are: (Table presented) When compared to rate data for the corresponding alkanes the results show that the ‐ONO group decreases the rate constant for H atom abstraction by the OH radical from groups bonded to the ‐ONO group and also decreases that for groups in the β position. Similar results were found for the reaction of Cl atoms with these compounds. The results are discussed in terms of reactivity trends.",
author = "Nielsen, {Ole J.} and Sidebottom, {Howard W.} and Michael Donlon and Jack Treacy",
year = "1991",
month = jan,
day = "1",
doi = "10.1002/kin.550231204",
language = "English",
volume = "23",
pages = "1095--1109",
journal = "International Journal of Chemical Kinetics",
issn = "0538-8066",
publisher = "JohnWiley & Sons, Inc.",
number = "12",

}

RIS

TY - JOUR

T1 - Rate constants for the gas‐phase reactions of OH radicals and Cl atoms with n‐alkyl nitrites at atmospheric pressure and 298 K

AU - Nielsen, Ole J.

AU - Sidebottom, Howard W.

AU - Donlon, Michael

AU - Treacy, Jack

PY - 1991/1/1

Y1 - 1991/1/1

N2 - Rate constants for the reactions of OH radicals and Cl atoms with CH3ONO, C2H5ONO, n‐C3H7ONO, n‐C4H9ONO, and n‐C5H11ONO have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a relative rate method involving simultaneous measurement of the loss of the nitrite and the reference compound. The Cl rate constants were measured using the relative rate method. Values of the rate constants in units of 10−13 cm3 molecule−1 s−1 are: (Table presented) When compared to rate data for the corresponding alkanes the results show that the ‐ONO group decreases the rate constant for H atom abstraction by the OH radical from groups bonded to the ‐ONO group and also decreases that for groups in the β position. Similar results were found for the reaction of Cl atoms with these compounds. The results are discussed in terms of reactivity trends.

AB - Rate constants for the reactions of OH radicals and Cl atoms with CH3ONO, C2H5ONO, n‐C3H7ONO, n‐C4H9ONO, and n‐C5H11ONO have been determined at 298 ± 2 K and a total pressure of approximately 1 atm. The OH rate data were obtained using both the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy and a relative rate method involving simultaneous measurement of the loss of the nitrite and the reference compound. The Cl rate constants were measured using the relative rate method. Values of the rate constants in units of 10−13 cm3 molecule−1 s−1 are: (Table presented) When compared to rate data for the corresponding alkanes the results show that the ‐ONO group decreases the rate constant for H atom abstraction by the OH radical from groups bonded to the ‐ONO group and also decreases that for groups in the β position. Similar results were found for the reaction of Cl atoms with these compounds. The results are discussed in terms of reactivity trends.

UR - http://www.scopus.com/inward/record.url?scp=0026398743&partnerID=8YFLogxK

U2 - 10.1002/kin.550231204

DO - 10.1002/kin.550231204

M3 - Journal article

AN - SCOPUS:0026398743

VL - 23

SP - 1095

EP - 1109

JO - International Journal of Chemical Kinetics

JF - International Journal of Chemical Kinetics

SN - 0538-8066

IS - 12

ER -

ID: 228197299