Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K

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Standard

Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K. / Nielsen, Ole J.

I: Chemical Physics Letters, Bind 187, Nr. 3, 1991, s. 286-290.

Publikation: Bidrag til tidsskrift › Tidsskriftartikel › Forskning › fagfællebedømt

Harvard

Nielsen, OJ 1991, 'Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K', Chemical Physics Letters, bind 187, nr. 3, s. 286-290. https://doi.org/10.1016/0009-2614(91)90427-B

APA

Nielsen, O. J. (1991). Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K. Chemical Physics Letters, 187(3), 286-290. https://doi.org/10.1016/0009-2614(91)90427-B

Vancouver

Nielsen OJ. Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K. Chemical Physics Letters. 1991;187(3):286-290. https://doi.org/10.1016/0009-2614(91)90427-B

Author

Nielsen, Ole J. / Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K. I: Chemical Physics Letters. 1991 ; Bind 187, Nr. 3. s. 286-290.

Bibtex

@article{78e59930d504416ab74612a3b4c89fc3,
title = "Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K",
abstract = "Rate constants for the reactions of OH radicals with CH3CHF2 and CHC12CF3 have been determined overthe temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy. The data can be fit to the Arrhenius expressions: kOH+HFC-152a=3.9 × 10-12 exp[(-1370±260)/T] cm3 molecule-1s-1 and kOH+HCF-123=1.1 × 10-12 × exp[(-940±200/T] cm3 molecule-1s-1. The results are compared to the available literature data and discussed in terms of reactivity trends and in the light of the important role CH3CHF2 and CHCl2CF3 play as alternatives to the fully halogenated chlorofluorocarbons.",
author = "Nielsen, {Ole J.}",
year = "1991",
doi = "10.1016/0009-2614(91)90427-B",
language = "English",
volume = "187",
pages = "286--290",
journal = "Chemical Physics Letters",
issn = "0009-2614",
publisher = "Elsevier",
number = "3",

}

RIS

TY - JOUR

T1 - Rate constants for the gas-phase reactions of OH radicals with CH3CHF2 and CHC12CF3 over the temperature range 295-388 K

AU - Nielsen, Ole J.

PY - 1991

Y1 - 1991

N2 - Rate constants for the reactions of OH radicals with CH3CHF2 and CHC12CF3 have been determined overthe temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy. The data can be fit to the Arrhenius expressions: kOH+HFC-152a=3.9 × 10-12 exp[(-1370±260)/T] cm3 molecule-1s-1 and kOH+HCF-123=1.1 × 10-12 × exp[(-940±200/T] cm3 molecule-1s-1. The results are compared to the available literature data and discussed in terms of reactivity trends and in the light of the important role CH3CHF2 and CHCl2CF3 play as alternatives to the fully halogenated chlorofluorocarbons.

AB - Rate constants for the reactions of OH radicals with CH3CHF2 and CHC12CF3 have been determined overthe temperature range 295-388 K and a total pressure of 1 atm. The OH rate data were obtained using the absolute rate technique of pulse radiolysis combined with kinetic spectroscopy. The data can be fit to the Arrhenius expressions: kOH+HFC-152a=3.9 × 10-12 exp[(-1370±260)/T] cm3 molecule-1s-1 and kOH+HCF-123=1.1 × 10-12 × exp[(-940±200/T] cm3 molecule-1s-1. The results are compared to the available literature data and discussed in terms of reactivity trends and in the light of the important role CH3CHF2 and CHCl2CF3 play as alternatives to the fully halogenated chlorofluorocarbons.

U2 - 10.1016/0009-2614(91)90427-B

DO - 10.1016/0009-2614(91)90427-B

M3 - Journal article

AN - SCOPUS:0038061168

VL - 187

SP - 286

EP - 290

JO - Chemical Physics Letters

JF - Chemical Physics Letters

SN - 0009-2614

IS - 3

ER -

ID: 228197205